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Dissociation of Deuterated Heavy Water Clusters D+(D2O)3 and Identification of Charged and Neutral Products


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Abstract


Heavy water is different from light water in several respects. The density of heavy water is 10.6 % greater than the light water and its physical properties are different. Several studies have been dedicated on the properties and the dynamics of heavy water molecules. This article shows the possibility of dissociation of Deuterated heavy water clusters in several competing channels and the ability to detect to neutral heavy water molecules using the technique of CID-COINTOF (Collision Induced Dissociation- COrrelated Ion and Neutral Time Of Flight) mass spectrometry. The present work is focused essentially on the dissociation of Deuterated heavy trimer water cluster D+(D2O)3. Through this famous new technique based on the event-by-event detection, the different dissociation channels and the correlation between the charged and neutral produced fragments are explored by studying the arrival time difference between the detected fragments. The charged D+(D2O)n=1.2 and neutral (D2O)n=1.2 fragments produced by dissociation of a single precursor ion, in a specific dissociation channel, are identified by analyzing their output signal amplitude distributions at the same MCP detector. A detailed analysis of the signal amplitude distributions as a function of the masses and the velocities of the detected particles is presented here. The study of the output signal amplitude distributions allows the identification of all charged and neutral fragments having specific size and velocity and that are coming from a specific dissociation process. This article shows also the ability to detect neutral heavy water molecules D2O and neutral heavy dimer water molecules (D2O)2.
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Keywords


Heavy Water; Deuterium; Cluster Dissociation; Signal Amplitude; Cluster Dissociation; Mass Spectrometry; Collision Induced Dissociation CID; COINTOF

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References


S. Tomita et al, High energy collisions of protonated water clusters, Euro. Phys. J. D 16 (2001), 119-122.
https://doi.org/10.1007/s100530170074

Z. P. Wang et al, Microscopic Studies of Atom-Water Collisions, Int. J. Mass Spectrom. 285 (2009), 143-148.
https://doi.org/10.1016/j.ijms.2009.05.008

F. Dong et al, Dynamics and fragmentation of van der Waals clusters: (H2O)n, (CH3OH)n, and (NH3)n upon ionization by a 26.5eV soft x-ray laser, J. Chem. Phys. 124 (2006), 224319-224336.
https://doi.org/10.1063/1.2202314

B.T. Chait, Mass Spectrometry: Bottom-Up or Top-Down? Science (2006), 65-66.
https://doi.org/10.1126/science.1133987

J. Ren et al, Fragmentation Patterns and Mechanisms of Singly and Doubly Protonated Peptoids Studied by Collision Induced Dissociation, J. Am. Soc. Mass Spectrom., 27 (2016), 646-661.
https://doi.org/10.1007/s13361-016-1341-0

M.-Q. Zuo et al, Characterization of collision-induced dissociation of deprotonated peptides of 4-16 amino acids using high-resolution mass spectrometry, Int. J. Mass Spectrom. 445 (2019), 116186.
https://doi.org/10.1016/j.ijms.2019.116186

SH Giese et al, A Study into the Collision-induced Dissociation (CID) Behavior of Cross-Linked Peptides, Mol Cell Proteomics., 15 (2016), 1094-104.
https://doi.org/10.1074/mcp.M115.049296

D. Nikolić et al, Collision-induced dissociation of phenethylamides: role of ion-neutral complexes, Mass Spectrometry, 31 (2017), 1385-1395.
https://doi.org/10.1002/rcm.7915

F. Gobet et al, Event-by-Event Analysis of Collision-Induced Cluster-Ion Fragmentation: Sequential Monomer Evaporation versus Fission Reactions, Phys. Rev. Lett. 86 (2001), 4263-4266.
https://doi.org/10.1103/PhysRevLett.86.4263

M. Farizon, et all, Method for tandem time of flight analysis and analysis appliance using said method, Université Claude Bernard Lyon 1, Dépôt de brevet n° 09 58991 du 15 Décembre 2009, PCT/FR2010/052733 patent; Jul, 7 2011: WO 2011/080455.

Harb, M., Abou-Saleh, K., Dissociation Process of Protonated Water Dimer and Trimer Clusters via COINTOF Mass Spectrometry: Identification of Neutral Water Dimer, (2019) International Review of Physics (IREPHY), 13 (1), pp. 1-7.

Susan T. Graul et al, Deuterium isotope fractionation within protonated water clusters in the gas phase, J. Am. Chem. Soc. 112, 2, (1990). 631 - 639.
https://doi.org/10.1021/ja00158a021

Justinas Ceponkus et al, Structure and dynamics of small water clusters, trapped in inert matrices, Chemical Physics Letters, 581 (2013) 1 - 9.
https://doi.org/10.1016/j.cplett.2013.06.046

Vladyslav V Goncharuk et al, Revealing water's secrets: deuterium depleted water, Chem Cent J. volume 7, (2013) 103.
https://doi.org/10.1186/1752-153X-7-103

K. Hansan et al, Magic numbers and stabilities of heavy water clusters, (D2O)ND+, N=3−48, International Journal of Mass Spectrometry, Volume 440, (2019) 14 - 19.
https://doi.org/10.1016/j.ijms.2019.03.003

Xiang Huang et al, Photoinduced water oxidation in pyrimidine-water clusters: a combined experimental and theoretical study, Physical Chemistry Chemical Physics, (2020), 22(22).
https://doi.org/10.1039/D0CP01562H

Ankur Solanki et al, Heavy Water Additive in Formamidinium: A Novel Approach to Enhance Perovskite Solar Cell Efficiency, advanced materials, (2020), 32(23), 1907864.
https://doi.org/10.1002/adma.201907864

ROOT©: A Data Analysis Framework.
http://root.cern.ch/drupal/C

Teyssier et al, A novel Correlated ion and neutral time of flight" method: Event-by-event detection of neutral and charged fragments in collision induced dissociation of mass selected ions, Rev. Sci. Instrum. 85 (2014), 015118-015124.
https://doi.org/10.1063/1.4863015

G. Bruny et al, A new Experimental Setup Designed for the Investigation of Irradiation of Nanosystems in the Gas Phase: A High Intensity Mass-and-Energy selected Cluster Beam, Rev. Sci. Instrum. (2012), 013305-013307.
https://doi.org/10.1063/1.3677845

W.C. Wiley et al, Time
ofFlight Mass Spectrometer with Improved Resolution, Rev. Sci. Instrum. 26 (1955), 1150-1157.
https://doi.org/10.1063/1.1715212

J. Laskin et al, Kinetic energy release distributions in mass spectrometry, J. Mass Spectrom. 36 (2001), 459-478.
https://doi.org/10.1002/jms.164

I.G. Gurtubay et al, Dissociation energy of the water dimer from quantum Monte Carlo calculations, J. Chem. Phys. 127 (2007), 124306-124314.
https://doi.org/10.1063/1.2770711

SIMION 3D 7.0 ©:D.A. Dahl, Scientific Instrument Services Inc., Boise Idaho (2000).

J.C. Jiang et al, Infrared Spectra of H+(H2O)5-8 Clusters: Evidence for Symmetric Proton Hydration, J. Am. Chem. Soc. 122 (2000), 1398-1410.
https://doi.org/10.1021/ja990033i

D. Marx et al., The nature of the hydrated excess proton in water, Nature; 397 (1999), 601-604.
https://doi.org/10.1038/17579

H.C. Chang et al., Recent advances in understanding the structures of medium-sized protonated water clusters, Int. Rev. Phys. Chem. 24 (2005), 553-578.
https://doi.org/10.1080/01442350500448116

Fujii et al, Infrared Spectroscopic Studies on hydrogen-bonded water networks in the gas phase clusters, Int. Rev. Phys. Chem. 32 (2013), 266-307.
https://doi.org/10.1080/0144235X.2012.760836

J.M. Headrick et al, Spectral signatures of hydrated proton vibrations in water clusters, Science 309 (2005), 1765-1769.
https://doi.org/10.1126/science.1113094

Mi, D.; Chingin, K. Water Radical Cations in the Gas Phase: Methods and Mechanisms of Formation, Structure and Chemical Properties. Molecules 2020, 25, 3490.
https://doi.org/10.3390/molecules25153490


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