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Adsorption of Cu(II) Ions on Areca Catechu Stem-Based Activated Carbon: Optimization Using Response Surface Methodology

Abrar Muslim(1*), Marwan Marwan(2), Ramli Saifullah(3), Muhammad Yahya Azwar(4), Darmadi Darmadi(5), Bayu Pramana Putra(6), Samsul Rizal(7)

(1) Chemical Engineering Department, Engineering Faculty, Universitas Syiah Kuala, Indonesia
(2) Chemical Engineering Department, Engineering Faculty, Universitas Syiah Kuala, Indonesia
(3) Chemical Engineering Department, Engineering Faculty, Universitas Syiah Kuala, Indonesia
(4) Chemical Engineering Department, Engineering Faculty, Universitas Syiah Kuala, Indonesia
(5) Chemical Engineering Department, Engineering Faculty, Universitas Syiah Kuala, Indonesia
(6) PT. Jasa Lingkungan Indonesia (JLI), Banda Aceh, Indonesia
(7) Mechanical Engineering Department, Engineering Faculty, Universitas Syiah Kuala, Indonesia
(*) Corresponding author



This study proposes an optimization of Cu(II) ions adsorption from aqueous solution on activated carbon based on a response surface methodology. It has been prepared using Areca Catechu stem. Box Behnken method using Design Expert application has resulted in 29 runs of Cu(II)  adsorption experiments. The Cu(II) ions adsorption has fitted very well with the pseudo first-order kinetic and Freundlich isotherm models. The experiment result has been based on the analysis of variance four independent variables of the initial concentration of Cu(II) ions, activator concentration, adsorption temperature and pH with the response variable of adsorption capacity. Validation of quadratic polynomial model obtained has been done with the correlation coefficient, R2 value being 0,998. Optimization has been done by maximizing the concentration of Cu(II) ions at 1000 mg/l, and setting the activator concentration, adsorption temperature and pH at 0.5 M, 45 °C and 5, respectively. As a result, the optimized Cu(II) ions adsorption capacity by Areca Catechu stem-based activated carbon obtained has been approximately 68.093 mg/g.
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Adsorption; Activated Carbon; Areca Catechu Stem; Modeling; Optimization; Box Benkhen

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S. J. Hawkes, What is a Heavy Metal?, Journal of Chemical Education, Vol. 74(11): pp. 1374–1380, 1997.

N. K. Srivastava, and B. C. Majumder, Novel Biofiltration Methods for the Treatment of Heavy Metals from Industrial Wastewater, Journal of Hazardous Materials, Vol. 151(1): pp. 1–8, 2008.

M. Bala, R. A. Shehu, and M. Lawal, Determination of the Level of Some Heavy Metals in Water Collected from Two Pollution - Prone Irrigation Areas Around Kano Metropolis, Bayero Journal of Pure and Applied Sciences, Vol. 1(1): pp. 6–38, 2008.

G. Yan-Biao, F. Hong, C. Chong, J. Chong-Jian, X. Fan, and L. Ying, Heavy Metal Concentration in Soil and Agricultural Products Near an Industrial District, Polish Journal of Environmental Studies, Vol. 22(5): pp. 1357–1362, 2013.

L. Dimple, Adsorption of Heavy Metals: A Review, International Journal of Environmental Research and Development, Vol. 4(1): pp. 41–48, 2014.

M. Minamisawa, H. Minamisawa, S. Yoshida, and N. Takai, Adsorption Behavior of Heavy Metals on Biomaterials, Journal of Agricultural and Food Chemistry, Vol. 52(18): pp. 5606–5615, 2004.

T. Theophanides, J. Anastassopoulou, Copper and Carcinogenesis, Critical Reviews in Oncology/Hematology, Vol. 42(1): pp. 57–64, 2002.

L. K. Carl, J. M. Harry, and M. W Elizabeth, A Review: The Impact of Copper on Human Health, New York: International Copper Association Ltd., 2003.

E. Munaf, and T. Takeuchi, Monitoring of University Effluents, In: Hazardous Waste Control in Research and Education. Korenaga T., Tsukube H., Shinoda S. & I. Nakamura, eds. Boca Raton, FL: CRC Press, 1994.

J. M. Tobin, and J. C. Roux, Mucor Biosorbent for Chromium Removal, Water Research, Vol. 32(5): pp. 1407–1416, 1998.

W.C. Leung, M. F. Wong, H. Chua, W. Lo, P. H. F. Yu, and C. K. Leung, Removal and Recovery of Heavy Metals by Bacteria Isolated from Activated Sludge Treating Industrial Effluents and Municipal Wastewater, Water Science and Technology, Vol. 41(12): pp. 233–240, 2000.

H. Eccles, Treatment of Metal-Contaminated Wastes: Why Select a Biological Process?, Trends in Biotechnology, Vol. 17(12): pp. 462–465, 1999.

Research In China, China Activated Carbon Industry Report, 2014-2017, 2015.

M. Kobya, E. Demirbas, E. Senturk, and M. Ince, Adsorption of Heavy Metal Ions from Aqueous Solutions by Activated Carbon Prepared from Apricot Stone, Bioresource Technology, Vol. 96(13): pp. 1518–1521, 2005.

H. Gupta, and P. R. Gogate, Intensified Removal of Copper from Waste Water Using Activated Water Melon Based Biosorbent in The Presence of Ultrasound, Ultrasonics Sonochemistry, Vol. 30: pp. 113–122, 2016.

F. Bouhamed, Z. Elouear, and J. Bouzid, Adsorptive Removal of Copper(II) from Aqueous Solution on Activated Carbon Prepared from Tunisian Date Stones: Equilibrium, Kinetic and Thermodynamics, Journal of the Taiwan Institute of Chemical Engineers, Vol. 43(5): pp. 741–749, 2012.

M. Imamoglu, and O. Tekir, Removal of Copper (II) and Lead (II) Ion from Aqueous Solution by Adsorption on Activated Carbon from a New Precursor Hazelnut Husks, Desalination, Vol. 228(1-3): pp. 108–113, 2008.

E. Demirbas, N. Dizge, M. T. Sulak, and M. Kobya, Adsorption Kinetic and Equilibrium of Copper from Aqueous Solution Using Hazelnut Shell Activated Carbon, Chemical Engineering Journal, Vol. 148(2–3): pp. 480–487, 2009.

A. Muslim, S. Aprilia, T. A. Suha, and Z. Fitri, Adsorption of Pb (II) Ions from Aqueous Solution Using Activated Carbon Prepared from Areca Catechu Shell: Kinetic, Isotherm and Thermodynamic Studies. Journal of the Korean Chemical Society, Vol. 61(3): pp. 89–96, 2017.

A. Muslim, Australian Pine Cones-Based Activated Carbon for Adsorption of Copper in Aqueous Solution, Journal of Engineering Science and Technology, Vol. 12(2): pp. 280–295, 2017.

A. Muslim, Ellysa, and D. S. Syahiddin, Cu(II) ions Adsorption Using Activated Carbon Prepared from Pithecellobium Jiringa (Jengkol) Shells with Ultrasonic Assistance: Isotherm, Kinetic and Thermodynamic Studies, Journal of Engineering and Technological Sciences, Vol. 49(4): pp. 472–490, 2017.

D. S. Syahiddin, and A. Muslim, Adsorption of Cu(II) Ions onto Myristica Fragrans Shell-based Activated Carbon: Isotherm, Kinetic and Thermodynamic Studies, Journal of the Korean Chemical Society, Vol. 62(2): pp. 79–86, 2018.

R. Chakravarti and V. Sahai, Optimization of compactin production in chemically defined production medium by Penicillium citrinum using statistical methods, Process Biochemistry, Vol. 38(4): pp. 481–486, 2002.

N. Mohamad, A. Muchtar, M. J. Ghazali, D. H. J. Mohd, and C. H. Azhari, Epoxidized natural rubber-alumina nanoparticle composites: optimization of mixer parameters via response surface methodology, Journal of Applied Polymer Science, Vol. 115(1): pp. 183–189, 2010.

J. A. Razak, S. H. Ahmad, C. T. Ratnam, M. A. Mahamood, J. Yaakub, and N. Mohamad, Effects of EPDM-g-MAH compatibilizer and internal mixer processing parameters on the properties of NR/EPDM blends: An analysis using response surface methodology, Journal of Applied Polymer Science, 132(27): Article ID 42199, 2015.

Zuorro, A., Modelling of Polyphenol Recovery from Olive Pomace by Response Surface Methodology, (2014) International Review on Modelling and Simulations (IREMOS), 7 (6), pp. 1023-1028.

C. Muthanna, J. Ahmed, K. Samar, Theydan, Optimization of Microwave Preparation Conditions for Activated Carbon from Albizia Lebbeck Seed Pods for Methylene Blue Dye Adsorption. Journal of Analytical and Applied Pyrolysis, Vol. 105: pp. 199–208. 2014.

Design-Expert. Stat Ease. Version 11.0.3 Minneapolis, MN. 2018.

M. Li, C. Feng, Z. Zhang, R. Chen, C. Gao, N. Sugiura and Q. Xue, Optimization of Process Parameters for Electrochemical Nitrate Removal Using Box–Behnken Design, Electrochimica Acta, Vol. 56: pp. 265–270. 2010.

Z. R. Lazic, Design of Experiment in Chemical Engineering: A Practical Guide. New York: Wiley-VCH. 2004.

S. Lagergren, About the Theory of So-Called Adsorption of Soluble Substances, Kungliga Svenska Vetenskapsakademies Handlingar, Vol. 24(4): pp. 1–39, 1989.

Y. S. Ho, D. A. J. Wase, and C. F. Forster, Kinetic Studies of Competitive Heavy Metal Adsorption by Sphagnum Moss Peat, Environmental Technology, pp. 17(1): pp. 71–77, 1996.

I. Langmuir, The Adsorption of Gases on Plane Surface of Glass, Mica and Platinum, Journal of the American Chemical Society, Vol. 40(9): pp. 1361–1403, 1918.

H. Freundlich, Adsorption in Solution, The Journal of Physical Chemistry, Vol. 57: pp. 384–410, 1906.

A. M. Joglekar, and A. T. May. Product excellence through design of experiments. Cereal Foods World, Vol. 32: pp. 857–868, 1987.

A. Koocheki, S. A. Mortazavi. F. Shahidi, S. M. A. Razav. R. Kadkhodaee. and J. M. Milani. Optimization of Mucilage Extraction from Qodume Shirazi Seed (Alyssum homolocarpum) Using Response Surface Methodology. Journal of Food Process Engineering, Vol. 33(5): pp. 861–882. 2010.

Muslim, A., Ardy, S., Syaubari, S., Response Surface Methodology-Based Model and Optimization of CO2 Absorption Using Methyldiethanolamine Activated by Piperazine, (2017) International Review on Modelling and Simulations (IREMOS), 10 (4), pp. 296-302.

B. Kiran, and K. Thanasekaran, Copper Biosorption on Lyngbya Putealis: Application of Response Surface Methodology (RSM). Int. Biodeterior. Biodegrad. Vol. 65(6): pp. 840–845, 2011.

Z. Ma. D. Chen. J. Gu. B. Bao, and Q. Zhang. Determination of Pyrolysis Characteristics and Kinetics of Palm Kernel Shell Using TGA-FTIR and Model-Free Integral Methods. Energy Conversion Management, Vol. 89: pp. 251–259. 2015.


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