Open Access Open Access  Restricted Access Subscription or Fee Access

Thermal and Emission Performances of Neat Yellow Oleander (Thevitia Peruvian) Biodiesel Treated with an Antioxidant in Compression Ignition Engine


(*) Corresponding author


Authors' affiliations


DOI: https://doi.org/10.15866/ireme.v17i1.22322

Abstract


Biodiesel is synthesized by the transesterification process from vegetable oils or animal fats. Biodiesel can be used in diesel engines either neatly or in blends with diesel. Although the usage of biodiesel has many other advantages such as environmental friendliness and renewability, it has the major issue of long-term storage. Biodiesel is oxidized to form sedimentation and precipitation when it comes into contact with air, light, humidity, metal, and moisture. Oxidized biodiesel is unfit to be used in engines that obstruct fuel lines and injectors. The storage stability of biodiesel can be controlled by antioxidants which repress the oxidation reactions. In this investigation, an antioxidant called TBHQ (Tertiary Butyl Hydroquinone) is applied to yellow oleander biodiesel (Thevetia peruviana) at different concentrations ranging from 1000-4000 PPM to enhance storage stability. However, the study aims to assess any effect of the antioxidant on the engine and emission performance of biodiesel in various concentrations of TBHQ in a single-cylinder Kirloskar diesel engine. The Brake-Specific Fuel Consumption (BSFC) increases with increased TBHQ concentration in biodiesel and corresponding Brake Thermal Efficiencies (BTE) are lower with an increase in concentration. However, Brake Power (BP) remains unchanged at all loads for all test fuels and is not affected by TBHQ. Emissions of carbon monoxide (CO) and carbon dioxide (CO2) have decreased with the use of biodiesel, and the effect of TBHQ is minimal. NOx emissions for biodiesel or biodiesel treated with TBHQ with various concentrations have been lower at 50% load on the engine compared to diesel, but at high load, they lose the distinction between them.
Copyright © 2023 Praise Worthy Prize - All rights reserved.

Keywords


Biodiesel; Engine; Emission; Brake Specific Fuel Consumption; Brake Power; Antioxidant

Full Text:

PDF


References


World Energy Outlook 2021, IEA (2021).

Worldometer home page. https://www.worldometers.info/oil/ (Accessed 2023)

M. Kannan, R. Sathish Babu & S. Sathish, Experimental investigations on the performance and emission characteristics of CI engine fuelled with biodiesel from neem oil, International Journal of Ambient Energy, Vol. 43, pp. 2351-2359, 2022.
https://doi.org/10.1080/01430750.2020.1726812

S. O. Bitire and TC Jen, TC, Performance and emission analysis of a CI engine fueled with parsley biodiesel-diesel blend, Mater Renew Sustain Energy, Vol. 11, pp. 143-153, 2022.
https://doi.org/10.1007/s40243-022-00213-4

A. Afzal, M.E. Soudagar, A. Belhocine, M. Kareemullah, N. Hossain, S. Alshahrani, C.A. Saleel, R. Subbiah, F. Qureshi, M.A. Mujtaba, Thermal Performance of Compression Ignition Engine Using High Content Biodiesels: A Comparative Study with Diesel Fuel, Sustainability, Vol. 13, pp. 7688, 2021.
https://doi.org/10.3390/su13147688

Junxing Hou, Zhenghe Wang, Shuanghui Xi, Shuhao Li, and Xiaokui Xu, Comparative Analysis of Combustion Behaviors and Emission Characteristics of Diesel Engines Fueled with Biodiesel or Biodiesel Blends, ACS Omega Vol. 37, pp. 33461-33469, 2022.
https://doi.org/10.1021/acsomega.2c04254

S. Ramalingam, S. Rajendran, P. Ganesan, and M. Govindasamy, Effect of operating parameters and antioxidant additives with biodiesels to improve the performance and reducing the emissions in a compression ignition engine - A review, Renewable and Sustainable Energy Reviews, Vol. 81, pp. 775-788, 2018.
https://doi.org/10.1016/j.rser.2017.08.026

Zhang, Y.; Zhong, Y.; Wang, J.; Tan, D.; Zhang, Z.; Yang, D, Effects of Different Biodiesel-Diesel Blend Fuel on Combustion and Emission Characteristics of a Diesel Engine. Processes, Vol. 9, pp. 1984, 2021.
https://doi.org/10.3390/pr9111984

T.T. Kivevele, M.M. Mbarawa, A. Bereczky, T. Laza, and J. Madarasz, Impact of antioxidant additives on the oxidation stability of biodiesel produced from Croton Megalocarpus oil, Fuel Processing Technology, Vol. 92, pp. 1244-1248, 2011.
https://doi.org/10.1016/j.fuproc.2011.02.009

M. Saikia, B. Bikash, D. K. Bora, and K. Kalita, Thermal performances of neat bio-diesels in compression ignition engine for diesel fuel substitution, 2nd International Conference on Power, Energy and Environment: Towards Smart Technology (ICEPE), 2018, pp. 1-6, 2018.
https://doi.org/10.1109/EPETSG.2018.8659194

D. Bora, L.M. Das, and M.K.G Babu, The storage stability of mahua oil methyl ester, Journal of Scientific and Industrial Research, Vol. 68, pp. 49-152, 2009.

L.M. Das, Dilip Kumar Bora, S. Pradhan, M. K. Naik, and S.N. Naik, Long-term storage stability of biodiesel produced from Karanja oil, Fuel, Vol. 88, no. 11, pp. 2315-2318, 2009.
https://doi.org/10.1016/j.fuel.2009.05.005

D. Chaithongdee, J. Chutmanop, and P. Srinophakun, Effect of antioxidant and additives on the oxidation stability of Jatropha biodiesel" Kasetsart J. (Nat. Sci.), Vol. 44, no. 2, pp. 243-250, 2010.

E. Christensen and R. L. McCormick, Long-term storage stability of biodiesel and biodiesel blends, Fuel Processing Technology, Vol. 128, pp. 339-348, 2014.
https://doi.org/10.1016/j.fuproc.2014.07.045

E.C. Zuleta, L. Baena, L.A. Riosa, and J. Calderón, The oxidative stability of biodiesel and its impact on the deterioration of metallic and polymeric materials: a review, J. Braz. Chem. Soc., Vol. 23, pp. 2159-2175, 2012.
https://doi.org/10.1590/S0103-50532012001200004

M. Mittelbach, M. and S. Schober, The influence of antioxidants on the oxidation stability of biodiesel, Journal of American Oil Chemists' Society, Vol. 80, no. 8, pp. 817-823, 2003.
https://doi.org/10.1007/s11746-003-0778-x

R. O. Dunn, Effect of antioxidants on the oxidative stability of methyl soyate (biodiesel), Fuel Processing Technology, Vol. 86, no. 10, pp. 1071-1085, 2005.
https://doi.org/10.1016/j.fuproc.2004.11.003

M.M. Rashed and M.A. Kalam, Stability of biodiesel, its improvement and the effect of antioxidant treated blends on engine performance and emission, RSC Advances, Vol. 5, no. 4, pp. 362-40, 2015.
https://doi.org/10.1039/C4RA14977G

S. Jain and M.P. Sharma, Oxidation stability of blends of Jatropha biodiesel with diesel, Fuel, Vol. 90, pp. 3014-3020, 2011.
https://doi.org/10.1016/j.fuel.2011.05.003

R.K. Bharti, R. Katiyar, D. W. Dhar, R. Prasanna & R. Tyagi (2021) In situ transesterification and prediction of fuel quality parameters of biodiesel produced from Botryococcus sp. MCC31, Biofuels, Vol. 12, pp. 1131-1140.
https://doi.org/10.1080/17597269.2019.1594592

R. Fattah, H.C. Ong, T.M.I. Mahlia, State of the Art of Catalysts for Biodiesel Production, Frontiers in Energy Research, Vol. 8, pp. 101-115, 2020.
https://doi.org/10.3389/fenrg.2020.00101

A. Fröhlich, and S. Schober, The influence of tocopherols on the oxidation stability of methyl esters, The journal of the American Oil Chemists' Society, Vol. 84, no. 6, pp. 579-585, 2007.
https://doi.org/10.1007/s11746-007-1075-z

A. Domingos, E.B. Saad, W.W.D. Vechiatto, H.M. Wilhelm, and L.P. Ramos, The influence of bha, bht, and bhq on the oxidation stability of soybean oil ethyl esters (Biodiesel), J. Braz. Chem. Soc., Vol. 18, pp. 416-423, 2007.
https://doi.org/10.1590/S0103-50532007000200026

F.R.M. França, L. Freitas, A.L.D. Ramos, G. Silva, and S.T. Brandão, Storage and oxidation stability of commercial biodiesel using Moringa oleifera Lam as an antioxidant additive, Fuel, Vol. 203, pp. 627-632, 2017.
https://doi.org/10.1016/j.fuel.2017.03.020

V. B. Borugadda, A.K. Dalai, and S. Ghosh, Effects of natural additives on performance of canola biodiesel and its structurally modified derivatives, Industrial Crops and Products, Vol. 125, pp. 303-313, 2018.
https://doi.org/10.1016/j.indcrop.2018.08.068

N. Jeyakumar Z. Huang, and Dhinesh Balasubramanian, Experimental evaluation over the effects of natural antioxidants on oxidation stability of binary biodiesel blend, International Journal of Energy Research. Vol. 46, 2022.
https://doi.org/10.1002/er.7956

A. Devi, V. K. Das, and D. Deka, Ginger extract as a nature-based robust additive and its influence on the oxidation stability of biodiesel synthesized from non-edible oil, Fuel, Vol. 187, pp. 306-314, 2017.
https://doi.org/10.1016/j.fuel.2016.09.063

S. K., K. Yadav, and G. Dwivedi, Impact analysis of oxidation stability for biodiesel & its blends, Materials Today: Proceedings, Vol. 5, pp.19255-19261, 2018.
https://doi.org/10.1016/j.matpr.2018.06.283

J.Yang, Q.Sophia He, K. Corscadden, and Caldwell, Improvement on oxidation and storage stability of biodiesel derived from an emerging feedstock camelina, Fuel Processing Technology, Vol.157, pp. 90-98, 2017.
https://doi.org/10.1016/j.fuproc.2016.12.005

G.M. Mathew, D. Raina, V. Narisetty , V. Kumar , S. Saran , A. Pugazhendi , R. Sindhu, A. Pandey , P. Binod, Recent advances in biodiesel production: Challenges and solutions, Sci Total Environ, Vol. 10, pp. 794:148751, 2021.
https://doi.org/10.1016/j.scitotenv.2021.148751

J. Fu, S. Q. Turn, B. M. Takushi, and C. L. Kawamata, Storage and oxidation stabilities of biodiesel derived from waste cooking oil, Fuel, Vol. 167, pp. 89-97, 2010.
https://doi.org/10.1016/j.fuel.2015.11.041

F. Sundus, M.A. Fazal, and H.H. Masjuki, Tribology with biodiesel: A study on enhancing biodiesel stability and its fuel properties, Renewable and Sustainable Energy Reviews, Vol. 70, pp. 399-412, 2017.
https://doi.org/10.1016/j.rser.2016.11.217

K. Ryu, The characteristics of performance and exhaust emissions of a diesel engine using a biodiesel with antioxidants, Bioresource Technology, Vol. 101, pp. S78-S82, 2010.
https://doi.org/10.1016/j.biortech.2009.05.034

V.V. Ramalho and N. Jorge, Antioxidants utilizado emoleos, gorduras e alimentos gordurosos, Quim Nova, Vol. 29, no. 4, pp. 755-760, 2011.
https://doi.org/10.1590/S0100-40422006000400023

I.M. R. Fattah, H.H. Masjuki, M.A. Kalam, M.A. Wakil, H.K. Rashedul, and M.J. Abedin, Performance and emission characteristics of a CI engine fueled with Cocos nucifera and Jatropha curcas B20 blends accompanying antioxidants, Industrial Crops and Products, Vol. 57, pp. 132-140, 2014.
https://doi.org/10.1016/j.indcrop.2014.03.022

Balaji, G. & Cheralathan, M. (2015). Experimental investigation of the antioxidant effect on oxidation stability and emissions in a methyl ester of neem oil-fueled DI diesel engine, Renewable Energy, Vol. 74, pp. 910-916, 2015.
https://doi.org/10.1016/j.renene.2014.09.019

Pardo, C., Pabon, J., Fonseca, M., Performance, Emission, and Economic Perspectives of a Diesel Engine Fueled with a Mixture of Hydroxy Gas and Biodiesel from Waste Palm Cooking Oil, (2021) International Review of Mechanical Engineering (IREME), 15 (10), pp. 520-529.
https://doi.org/10.15866/ireme.v15i10.21211

Pardo García, C., Pabon, J., Fonseca Vigoya, M., Evaluation of Performance Parameters and Emissions of a Diesel Engine Fueled with Preheated Palm Oil Mill Effluent Biodiesel Blends, (2021) International Review of Mechanical Engineering (IREME), 15 (10), pp. 538-544.
https://doi.org/10.15866/ireme.v15i10.21423

Orozco, W., Buelvas, E., Pabon, J., Fonseca Vigoya, M., García, J., Experimental Study of Emissions in a Diesel Engine Using Biodiesel Blends from Algae Spirulina Platensis, (2020) International Review of Mechanical Engineering (IREME), 14 (11), pp. 666-673.
https://doi.org/10.15866/ireme.v14i11.19271


Refbacks

  • There are currently no refbacks.



Please send any question about this web site to info@praiseworthyprize.com
Copyright © 2005-2024 Praise Worthy Prize