Corrosion Inhibition Properties of Cinnamon Extract  on Monel 400 in Hydrochloric Acid Solution

Sihem Kherraf; Nesrine Ammouchi; Emna Zouaoui

doi:10.15866/ireme.v13i6.17090

Corrosion Inhibition Properties of Cinnamon Extract on Monel 400 in Hydrochloric Acid Solution

Sihem Kherraf^(1*), Nesrine Ammouchi⁽²⁾, Emna Zouaoui⁽³⁾

^(*) Corresponding author

Authors' affiliations

DOI: https://doi.org/10.15866/ireme.v13i6.17090

Abstract

The purpose of this study is to investigate Cinnamon extract as a cheap and environmentally safe corrosion inhibitor for Monel 400 in aerated stagnant 1M hydrochloric solution. The inhibitor has been prepared from the Cinnamon bark and its anticorrosion performance has been studied by the weight loss method. The effect of the inhibitor concentration, the immersion time, and the temperature against inhibitor action is investigated. Adsorption isotherm, Thermodynamic and activation parameters ((Gads, Ea and (Ha) have also been calculated and discussed. The obtained results show that the Cinnamon extract behaves as a good inhibitor for the acidic corrosion of Monel 400. It has been found out that the corrosion rate and the inhibition efficiency depend on the concentration of the inhibitor, the immersion time, and the corrosive media temperature. The maximum inhibition efficiency of 81.55% has been obtained at 2.5 g /L of Cinnamon extract, after 2 hours exposure time, and at 298 K. It has been found out that the inhibitor follows the Freundlich isotherm. The negative free energy of adsorption indicates that the Cinnamon extract is physically adsorbed on metal/solution interface and that the adsorption is spontaneous. The value of apparent activation energy increases with the increment in the inhibitor concentration. The enthalpy of the activation reflects the endothermic nature of the Monel dissolution process.
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Keywords

Activation and Thermodynamic Parameters; Adsorption Isotherm; Cinnamon; Corrosion Inhibitors; Mass Loss Method; Monel 400

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References

E.S.M. Sherif, A. A. Almajid, A. K. Bairamov, and A. Eissa, A Comparative Study on the Corrosion of Monel 400 In Aerated and Deaerated Arabian Gulf Water and 3.5% Sodium Chloride Solutions, International Journal Of Electrochemical Science, Vol. 7, pp. 2796-2810, 2012.

A. Eiman, R.Mohammad, B. Ghasem, R. Bahram, M. Mohammad and M. Milad, Glycyrrhiza Glabra Leaves Extract as a Green Corrosion Inhibitor for Mild Steel in 1 M Hydrochloric Acid Solution: Experimental, Molecular Dynamics, Monte Carlo and Quantum Mechanics Study, Journal of Molecular Liquids, Vol. 255, pp.185-198, 2018.
https://doi.org/10.1016/j.molliq.2018.01.144

M. Bouanis, M. Tourabi, A. Nyassi, A. Zarrouk, C. Jama and F. Bentiss, Corrosion inhibition performance of 2, 5-bis (4-dimethylaminophenyl)-1, 3, 4-oxadiazole for carbon steel in HCl solution: Gravimetric, electrochemical and XPS studies, Applied Surface Science, Vol. 389, pp. 952-966, 2016.
https://doi.org/10.1016/j.apsusc.2016.07.115

F. E. T. Heakal and A. E. Elkholy, Gemini surfactants as corrosion inhibitors for carbon steel, Journal of Molecular Liquids, Vol. 230, pp. 395-407, 2017.
https://doi.org/10.1016/j.molliq.2017.01.047

M. S. S. Adam, H. M. A. El-Lateef and K. A. Soliman, Anionic oxide vanadium Schiff base amino acid complexes as potent inhibitors and as effective catalysts for sulfides oxidation: Experimental studies complemented with quantum chemical calculations, Journal of Molecular Liquids, Vol. 250, pp. 307-322, 2018.
https://doi.org/10.1016/j.molliq.2017.12.013

M. T.Salah, Corrosion Inhibition Efficiency and Adsorption Behavior of N, N-dimethyl-4-(((1-methyl-2-phenyl-2, 3-dihydro-1H-pyrazol-4-yl) imino) methyl)-N-Akylbenzenaminium bromide Surfactant at Carbon Steel/hydrochloric Acid Interface, Journal of Molecular Liquids, Vol. 207, pp. 185-194, 2015.
https://doi.org/10.1016/j.molliq.2015.03.036

H. A. Ismat and H. A. Mohamed, Effect of Acid Extract of Leaves of Juniperus procera on Corrosion Inhibition of Carbon Steel in HCl Solutions, International Journal of Electrochemical Science, Vol. 13, pp. 3910-3922, 2018.
https://doi.org/10.20964/2018.04.01

S. Ramazan, Investigation of Ccorrosion Inhibition Mechanism and Stability of Vitamin B1 on Mild Steel in 0.5 M HCl Solution, Corrosion Science, Vol. 81, pp. 75-84, 2014.
https://doi.org/10.1016/j.corsci.2013.12.006

N. K. Othman, S.Yahya and M. C. Ismail, Corrosion Inhibition of Steel in 3.5% NaCl by Rice Straw Extract. Journal of Industrial and Engineering Chemistry, Vol. 70, pp.299-310, 2019.
https://doi.org/10.1016/j.jiec.2018.10.030

S. Pal , H. Lgaz, P.Tiwari, I. M. Chung, G. Ji and R. Prakash , Experimental and Theoretical Investigation of Aqueous and Methanolic Extracts of Prunus Dulcis Peels as Green Corrosion Inhibitors of Mild Steel in Aggressive Chloride Media. Journal of Molecular Liquids, Vol. 276, pp. 347-361,2019.
https://doi.org/10.1016/j.molliq.2018.11.099

A. Dehghani, G. Bahlakeh, B. Ramezanzadeh and M. Ramezanzadeh, A Combined Experimental and Theoretical Study of Green Corrosion Inhibition of Mild Steel in HCl Solution by Aqueous Citrullus lanatus fruit (CLF) Extract. Journal of Molecular Liquids. Vol. 279, pp. 603-624, 2019.
https://doi.org/10.1016/j.molliq.2019.02.010

V.T. Vanessa, S.A. Roberto, F.S. Camila, L.F. Tatiana, A.S. Carlos, G.T. Alexandre and E. Eliane, Inhibitory Action of Aqueous Coffee ground Extracts On the Corrosion of Carbon Steel in HCl Solution, Corrosion Science, Vol. 53, n. 2, pp. 2385-2392, 2011.
https://doi.org/10.1016/j.corsci.2011.03.021

A.K. Singh, S. Mohapatra and B. Pani, Corrosion Inhibition Effect of Aloe Vera gel: Gravimetric and Electrochemical Study, Journal of Industrial and Engineering Chemistry, Vol. 33, pp. 288-297, 2016.
https://doi.org/10.1016/j.jiec.2015.10.014

A. Saxena, D. Prasad, R. Haldhar, G. Singh and A. Kumar, Use of Saraca ashoka extract as green corrosion inhibitor for mild steel in 0.5 M H2SO4. Journal of Molecular Liquids, Vol. 258, pp. 89-97, 2018.
https://doi.org/10.1016/j.molliq.2018.02.104

V. Vinod and M. Avik, In Vitro Inhibition of Food Borne mutagens Induced Mutagenicity by Cinnamon (Cinnamomum cassia) bark Extract, Drug and chemical toxicology, Vol. 41,n. 4 pp. 385-393, 2018.
https://doi.org/10.1080/01480545.2018.1439056

A. F. Mohamed, M.L. Rola, N. Clarice, P. Andrea and A.W. Ludger, NMR Approach for the Authentication of 10 Cinnamon Spice Accessions Analyzed via Chemometric Tools, LWT - Food Science and Technology, Vol. 90, pp. 491-498, 2018.
https://doi.org/10.1016/j.lwt.2017.12.069

M. Dahmani, A. Et-Touhami, S. S. Al-Deyab, B. Hammouti and A. Bouyanzer, Corrosion inhibition of C38 steel in 1 M HCl: A comparative study of black pepper extract and its isolated piperine. Int. J. Electrochem. Sci, Vol. 5, n. 8, pp. 1060-1069, 2018.

A. E. A. S. Fouda, A. A. Nazeer, A. Y. El-Khateeb and M. Fakih, Cinnamon plant extract as corrosion inhibitor for steel used in waste water treatment plants and its biological effect on Escherichia coli. Journal of the Korean Chemical Society, Vol.58, n. 4, pp. 359-365, 2014.
https://doi.org/10.5012/jkcs.2014.58.4.359

S. S. Shivakumar and K. N. Mohana, Studies on the inhibitive performance of Cinnamomum zeylanicum extracts on the corrosion of mild steel in hydrochloric acid and sulphuric acid media. Journal of Materials and Environmental Science, Vol.4, n. 3, pp. 448-459, 2013.

L. A. Al Juhaiman, R. A. Al-Shihry and H. M. Al Hazmei, The Inhibition Effect of Cinnamon Extract on Leaching of Aluminum Cook Wares in NaCl Solutions at Quasi-Cooking Condition. Journal of Surface Engineered Materials and Advanced Technology, Vol. 5, n. 04, pp. 177-189, 2015.
https://doi.org/10.4236/jsemat.2015.54020

N. Mahato, M. R. Sharma, T. P. Chaturvedi and M. M. Singh, Effect of dietary spices on the pitting behavior of stainless steel orthodontic bands. Materials Letters, Vol. 65, n. 14, pp. 2241-2244, 2011.
https://doi.org/10.1016/j.matlet.2011.04.034

A. C. M. Larissa, C. T. Mariane, J. T. A. Guilherme, T.d.C. Maico, P. B. Everson, F.O. Marilei, D. Eliane and P.R. Paulo Rogério, Application of an Acid Extract of Barley Agro-Industrial Waste as a Corrosion Inhibitor for Stainless Steel AISI 304 in H2SO4, International Journal of Electrochemical Science, Vol. 13, pp. 1577-1593, 2018.
https://doi.org/10.20964/2018.02.01

K. Boumhara, H. Harhar, M.Tabyaoui, A. Bellaouchou, A. Guenbour and A. Zarrouk, Corrosion Inhibition of Mild Steel in 0.5 M H 2 SO 4 Solution by Artemisia herba-alba Oil, Journal of Bio-and Tribo-Corrosion, Vol.5, n.1, pp.8, 2019.
https://doi.org/10.1007/s40735-018-0202-8

R.Yıldız, Adsorption and Inhibition Effect of 2, 4-diamino-6-hydroxypyrimidine for Mild Steel Corrosion in HCl Medium: Experimental and Theoretical Investigation. Ionics, Vol.25, n. 2,. 859-870, 2019.
https://doi.org/10.1007/s11581-018-2649-5

T. K. Bhuvaneswari, V. S. Vasantha and C. Jeyaprabha, Pongamia Pinnata as a Green Corrosion Inhibitor for Mild Steel in 1N Sulfuric acid Medium, Silicon, Vol.10, n.5 pp. 1793–1807, 2018.
https://doi.org/10.1007/s12633-017-9673-3

R. M. Hassan, S. M. Ibrahim, H. D. Takagi and S. A. Sayed, Kinetics of Corrosion Inhibition of Aluminum in Acidic Media by Water-Soluble Natural Polymeric Chondroitin-4-sulfate as Anionic Polyelectrolyte Inhibitor. Carbohydrate polymers, Vol. 192,pp. 356-363, 2018.
https://doi.org/10.1016/j.carbpol.2018.03.066

R. T. Loto and O. Olowoyo, Corrosion Inhibition Properties of the Combined Admixture of Essential Oil Extracts on Mild Steel in the Presence of SO42− anions. South African Journal of Chemical Engineering, Vol. 26, pp. 35-41, 2018.
https://doi.org/10.1016/j.sajce.2018.09.002

L. Vrsalović, S. Gudić, M. Kliškić, E. E. Oguzie and L. Carev, Inhibition of copper corrosion in NaCl solution by caffeic acid, Int. J. Electrochem. Sci, Vol. 11, pp. 459-474, 2016.

M. S. Affaizza, A. R. Afidah, N. M. I. Mohamad and H.H. Mohd, Depolymerized Oil Palm Frond (OPF) Lignin Products as Corrosion Inhibitors for Mild Steel in 1 M HCl, International journal of Electrochemical Science, Vol. 12, n. 10, pp. 9017-9039, 2017.
https://doi.org/10.20964/2017.10.66

W. Xiumei, W. Yichong, W. Qing, W. Ye, H. Xiaoqi and J. Chen, Viburnum Sargentii Koehne Fruit Extract as Corrosion Inhibitor For Mild Steel in acidic solution, International journal of Electrochemical Science, Vol. 13, pp. 5228-5242, 2018.
https://doi.org/10.20964/2018.06.36

Y. Qiang, S. Zhang, B. Tan and S. Chen, Evaluation of Ginkgo leaf extract as an eco-friendly corrosion inhibitor of X70 steel in HCl solution. Corrosion Science, Vol.133, pp. 6-16, 2018.
https://doi.org/10.1016/j.corsci.2018.01.008

A. K. Singh, S. Mohapatra and B. Pani, Corrosion inhibition effect of Aloe Vera gel: gravimetric and electrochemical study. Journal of Industrial and Engineering Chemistry, Vol. 33, pp. 288-297, 2016.
https://doi.org/10.1016/j.jiec.2015.10.014

H. Lgaz, R. Salghi, S. Jodeh and B. Hammouti, Effect of clozapine on inhibition of mild steel corrosion in 1.0 M HCl medium, Journal of Molecular Liquids, Vol. 225, pp. 271-280, 2017.
https://doi.org/10.1016/j.molliq.2016.11.039

A.Mishra, C. Verma, H. Lgaz, V. Srivastava, M. A. Quraishi and E. E. Ebenso, Synthesis, characterization and corrosion inhibition studies of N-phenyl-benzamides on the acidic corrosion of mild steel: Experimental and computational studies, Journal of Molecular Liquids, Vol. 251, pp. 317-332, 2018.
https://doi.org/10.1016/j.molliq.2017.12.011

A. Rodríguez-Torres, O. Olivares-Xometl, M.G. Valladares-Cisneros and J.G. González-Rodríguez, Effect of Green Corrosion Inhibition by Prunus Persica on AISI 1018 Carbon Steel in 0.5 M H2SO4, International Journal of Electrochemical Science, Vol. 13, n. 3, pp. 3023-3049, 2018.
https://doi.org/10.20964/2018.03.40

B. Tan, S. Zhang, W. Li, X. Zuo, Y. Qiang, L. Xu, J. Hao and S. Chen, Experimental and theoretical studies on inhibition performance of Cu corrosion in 0.5 M H2SO4 by three disulfide derivatives, Journal of Industrial and Engineering Chemistry, Vol. 77, pp. 449-460, 2019.
https://doi.org/10.1016/j.jiec.2019.05.011

M. Bagherzadeh and F. Jaberinia, Electrochemical study of Monel alloy corrosion in hydrochloric acid solution and pyrrolidine dithiocarboxylate self-assembled monolayers as its corrosion protector. Journal of Alloys and Compounds, Vol. 750, pp. 677-686, 2018.
https://doi.org/10.1016/j.jallcom.2018.04.074

P. Muthukrishnan, P. Prakash, K. Shankar and A. Kathiresan, Benign Approach of Plant-Derived Inhibitor: Assessing Their Anticorrosive Activity on Mild Steel in Acidic Media. Journal of Failure Analysis and Prevention, Vol. 18, n. 3, pp. 677-689, 2018.
https://doi.org/10.1007/s11668-018-0461-1

T. Rabizadeh and S. K. Asl, Casein as a Natural Protein to Inhibit the Corrosion of Mild steel in HCl solution. Journal of Molecular Liquids, Vol. 276, pp. 694-704, 2019.
https://doi.org/10.1016/j.molliq.2018.11.162

M. Mobin and M. Rizvi, Adsorption and corrosion inhibition behavior of hydroxyethyl cellulose and synergistic surfactants additives for carbon steel in 1 M HCl. Carbohydrate polymers, Vol. 156, pp. 202-214, 2017.
https://doi.org/10.1016/j.carbpol.2016.08.066

A. A. Khadom, A. N. Abd and N. A. Ahmed, Xanthiumstrumarium leaves extracts as a friendly corrosion inhibitor of low carbon steel in hydrochloric acid: Kinetics and mathematical studies. South African Journal Of Chemical Engineering, Vol. 25, pp. 13-21,2018.
https://doi.org/10.1016/j.sajce.2017.11.002

M. Srivastava, P. Tiwari, S. K. Srivastava, A. Kumar, G. Ji and R. Prakash, Low cost aqueous extract of Pisum sativum peels for inhibition of mild steel corrosion. Journal of Molecular Liquids, Vol. 254, pp. 357-368, 2018.
https://doi.org/10.1016/j.molliq.2018.01.137

C. Lai, B. Xie, L. Zou, X. Zheng, X. Ma and S. Zhu, Adsorption and corrosion inhibition of mild steel in hydrochloric acid solution by S-allyl-O, O′-dialkyldithiophosphates. Results in physics, Vol. 7, pp. 3434-3443, 2017.
https://doi.org/10.1016/j.rinp.2017.09.012

K. Ghulamullah, J.B. Wan, N. K. Salim, A. Pervaiz, M. Ladan, M. A. Syed, M.K. Ghulam and A.R. Muhammad, Electrochemical Investigation on the Corrosion Inhibition of Mild steel by Quinazoline Schiff base Compounds in Hydrochloric Acid Solution, Journal of colloid and interface science, Vol. 502, pp. 134-145, 2017.
https://doi.org/10.1016/j.jcis.2017.04.061

A. Biswas, P. Mourya, D. Mondal, S. Pal and G. Udayabhanu, Grafting Effect of Gum Acacia on Mild Steel Corrosion in Acidic Medium: Gravimetric and Electrochemical Study. Journal of Molecular Liquids, Vol. 251, pp; 470-479, 2018.
https://doi.org/10.1016/j.molliq.2017.12.087

A. S. El Din, M. E. El Dahshan and A. T. El Din, Dissolution of Copper and Copper-nickel Alloys in Aerated Dilute HCl Solutions. Desalination, Vol.130, pp.89-97, 2000.
https://doi.org/10.1016/s0011-9164(00)00077-1

V. B. Singh, and A. Gupta, The Electrochemical Corrosion and Passivation Behaviour of Monel (400) in Concentrated Acids and their Mixtures. Journal of Materials Science, Vol. 36, n.6, pp.1433-1442, 2001.

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