Comparative Study on the Vulcanization and Mechanical Characteristics of Natural Rubber Based Composites Containing Carbon-Silica Fillers Obtained by Different Methods


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Abstract


Different types of carbon-silica fillers obtained via pyrolysis-cum-water vapor of waste green tires tread and impregnation method were used in natural rubber based composites. Dual phase fillers have been characterized by energy dispersive X-ray spectroscopy in a scanning transmission electron microscope. The effect upon the vulcanization and mechanical properties, heat ageing resistance of the compounds and vulcanizates filled with these fillers was investigated.
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Keywords


Natural Rubber; Vulcanization Characteristics; Mechanical Properties; Carbon-Silica Hybrid Fillers

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References


J. Frohlich, W. Niedermeier, H.D. Luginsland, The effect of filler-filler and filler-elastomer interaction on rubber reinforcement, Composites: Part A, (2005) 449-460.
http://dx.doi.org/10.1016/j.compositesa.2004.10.004

J.B. Donnet, E. Custodero In The Science and Technology of Rubber, 4th ed., J.E. Mark, B. Erman, M. Roland, Eds. (Elsevier Inc., 2013, p. 383-416).
http://dx.doi.org/10.1016/b978-0-12-394584-6.00008-x

K. Mahmud, M.J. Wang, R.A. Francis, Elastomeric compound incorporating silicon-treated carbon black, US Patent 5 830 930. 1998.

M.J. Wang, Y. Kutsovsky, P. Zhang, G. Mehos, L.J. Murphy, K. Mahmud, Using carbon-silica dual phase filler improve global compromise between rolling resistance, wear resistance and wet skid resistance for tires, Kaut.Gummi Kunstst. (2002) 33-40.

M.J. Wang, K. Mahmud, L.J. Murphy, W.J. Patterson, Carbon-silica dual phase filler-a new generation reinforcing agent for rubber, Kaut.Gummi Kunstst. (1998) 348-360.

D. Kolev, R. Ljutzkanova, S. Abadjiev, Method and installation for pyrolysis of tires, Bulgarian Patent 65901 B1. 2005.

D. Kolev, R. Ljutzkanova, S. Abadjiev, Method and installation for pyrolysis of tires, European Patent EP 1879978 A1. 2008.

D. Isayev, In The Science and Technology of Rubber 4th ed., J.E. Mark, B. Erman, M. Roland, Eds. (Elsevier Inc., 2013, p.753-755).

M. Ivanov, M. Mihaylov, L. Ljutzkanov, Silica obtained via pyrolysis of waste „green“ tyres - a perspective filler for rubber industry, Kaut.Gummi Kunstst. (2010) 303-307.
http://dx.doi.org/10.1177/0095244311398636

M. Ivanov, M. Mihaylov, Silica obtained via pyrolysis of waste “green” tyres - a filler for tyre tread rubber blends, J. Elast. Plast. (2011) 303-316.
http://dx.doi.org/10.1177/0095244311398636

O.A. Al-Hartomy, A.A. Al-Ghamdi, S.A. Farha Al Said, N. Dishovsky, M. Mihaylov, M. Ivanov, L. Ljutzkanov, Effect of the carbon-silica reinforcing filler obtained from the pyrolysis-cum-water vapour of waste green tyres upon the properties of natural rubber based composites. Progress in Rubber, Plast. Recycl. Tech. (2014) (in press).

Al-Hartomy, O., Al-Ghamdi, A., Al Said, S., Dishovsky, N., Mihaylov, M., Ivanov, M., Kolev, P., Ljutzkanov, L., Pyrolysed Carbon-Silica Filler Obtained by Pyrolysis-Cum-Water Vapour of Waste Green Tires vs. Conventional Fillers. Comparison of Their Effects Upon the Properties of Epoxidized Natural Rubber Based Vulcanizates, (2014) International Review of Chemical Engineering (IRECHE), 6 (4), pp. 160-168.

O.A. Al-Hartomy, A.A. Al-Ghamdi, S.A. Farha Al Said, N. Dishovsky, M. Mihaylov, M. Ivanov, L. Ljutzkanov, Influence of the Carbon-Silica Reinforcing Filler Obtained via Pyrolysis of waste “green” tyres on the properties of EPDM based composites, Kaut.Gummi Kunstst. (2014) (accepted for publication).

H. Marsh, E. Heintz , F. Rodrigues-Reinoso Eds., Introduction to Carbon Technologies (University of Alicante, 1997).

P. Malinova, R. Nikolov, N. Dishovsky, L. Lakov, Modification of carbon-containing fillers for elastomers, Kaut.Gummi Kunstst. (2004) 443-445.

O.A. Al-Hartomy, A.A. Al-Ghamdi, S.A. Farha Al Said, N. Dishovsky, P. Malinova , R. Nikolov, Obtaining of carbon-silica dual phase filler by impregnation method and investigation of its influence on the properties of SBR based composites, J. Mat. Design App. (2014).
http://dx.doi.org/10.1177/1464420714548499

ISO 15651/1-91

Bulgarian State Standard 9665:1176

S. Brunauer, P.H. Emmett, E. Teller, Adsorption of gases in multimolecular layers, J. Am. Chem. Soc. (1938) 309-319.
http://dx.doi.org/10.1021/ja01269a023

ISO 1125:1999

Ullmann’s Encyclopedia of Industrial Chemistry (Wiley-VCH, 1999-2014).
http://dx.doi.org/10.1002/14356007

H. Dohi, S. Horiuchi, Heterogeneity of a vulcanized rubber by the formation of a ZnS clusters, Polymer (2007) 2526-2530.
http://dx.doi.org/10.1016/j.polymer.2007.03.004

M.T. Ramesan, A. Nihmath, J. Francis, Preparation and characterization of zinc sulphide nanocomposites based on acrylonitrile butadiene rubber, International Conference on Recent Trends in Applied Physics & Material Science RAM 2013, Bikaner, Rajasthan, India, 1–2 February (2013).
http://dx.doi.org/10.1063/1.4810197

S. David, P. Fritzen, L. Heiming, T. Rentschler, Plastic comprising ZnS, US Patent 8383712.2010.


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