Bimetallic Platinum Catalysts for Paraffin Dehydrogenation


(*) Corresponding author


Authors' affiliations


DOI's assignment:
the author of the article can submit here a request for assignment of a DOI number to this resource!
Cost of the service: euros 10,00 (for a DOI)

Abstract


Promoting action of elements of Cu, Zn, Ga, Ge, Bi, S subgroups and of Re on platinum catalysts in paraffins  dehydrogenation is considered. The mechanism of influence on activity, selectivity and stability (coke tolerance effect) is discussed. It was demonstrated the prevailing role of geometric (ensemble) factor
Copyright © 2014 Praise Worthy Prize - All rights reserved.

Keywords


Paraffins Dehydrogenation; Bimetallic Platinum Catalysts; Coke Tolerance Effect

Full Text:

PDF


References


M. M. Bhasin, J. H. McCain, B. V. Vora, T. Imai, P. R. Pujado, Dehydrogenation and oxydehydrogenation of paraffins to olefins, Appl. Catal. A 221 (2001) 397-419.

B. M. Weckhuysen, R. A. Schoonheydt, Alkane dehydrogenation over supported chromium oxide catalysts, Catal. Today 51 (1999) 223-232.

D. Sanfilippo, Dehydrogenation of paraffins: key technology for petrochemicals, CATTECH 4 (2000) 56-72.[4] R. A. Buyanov, N. A. Pakhomov, Catalysts and processes for paraffin and olefin dehydrogenation, Kinet. Catal. 42 (2001) 64-75.

W. Weirauch, HPImpact: HPImpact: Latest supply/demand trends analyzed for global oil industry, Hydrocarb. Proc. March of 1999, 29-35.

Bill Hyde, Light Olefins Market Review, June 7 ,2013 (Google). [7] . J. Farrauto, C. H. Bartholomew, Fundamentals of Industrial Catalytic Processes ( Blackiue, London, 1997, p.450).

R. A. Meyers (ed.) Handbook of Petroleum Refining Process (2-nd edition, McGrill, New-York, 1997, Part 4).

M. F. L. Johnson, V. M. Le Roy, On the state of Re in the PtRe reforming catalysts, J. Catal. 35 (1974) 434-440.

R. Bacaud, P. Bussiere, F. Figueras, J. P. Mathiev, Preparation of Heterogeneous Catalysts, Proc. Intern. Symp.( Amsterdam, Elsevier Sci. Publ. Co., 1976, pp. 509-516).

N. M. Zaidman, Yu. A. Savostin, N. G. Kozhevnikova, Methodical approach to the study of the influence of additions on the properties of platinum/alumina catalysts, Kinet. Catal. 21 (1980) 1127-1132.

R. J. Bertolacini, R. J. Pellet, Catalyst Deactivation, Stud. Surf. Sci., vol. 6, B. Delmon and G. E. Froment (Eds) ( Amsterdam, Elsevier Sci. Publ. Co., 1980, pp. 73-77).

V. V. Chesnokov, R. A. Buyanov, N. A. Pakhomov, V. I. Zaikovskii, Reasons for increase in the stability to coking of an alumino-platinum catalyst on modification with tin . Kinet. Catal. 32 (1991) 1337-1341.

M. R. Jovanovic, P. S. Putanov, Nature and distribution of coke formed on mono-metallic platinum and bimetallic platinum- rhenium catalysts, Appl. Catal.A 159 (1997) 1-7.

N. A. Pakhomov, Reversible and irreversible deactivation of supported bimetallic catalysts for the dehydrogenation of lower paraffins, Kinet. Catal. 42 (2001) 334-343.

G. D. Gould, C. S. McCoy, Rheniforming scores: high in commercial runs, Oil and Gas J. 68 (1970) 49-53.

E. M. Blue, Regenerable catalyst highlights new rheniforming process, Hydrocarb. Proc. 48(1969) 141-148..

I. A. Nevison, I. A. Obaditch, M. H. Dalson, Magnaforming units compared, Hydrocarb. Proc. 53 (1974)111-114.

T. F. Garetto, C. R. Apestiguia, Determination of the accessible metal fraction and metal particle size on coked Pt/Al2O3-Cl catalysts, Appl. Catal. A 20 (1986) 133-143.

S. B. Kogan, N. M. Podkletnova, O. M. Oranskaya, I. V. Semenskaya, N. R. Bursian, Effect of tin on the activity of platinized alumina catalysts in the dehydrogenation of normal- dodecane, Kinet. Catal .22 (1981) 501-505.

N.R. Bursian, S. B. Kogan, B. B. Zharkov, N. M. Podkletnova, G. A. Lastovkin, Promoter action mechanism in hydrocarbon dehydrogenation bimetallic catalysts. 8-th Intern. Congress on Catal. ( Weinheim, Verlag Chemie, 1984, vol. 2, pp. 481-490).

H. Lieske, A. Sarkany, J. Voelter, Hydrocarbon adsorption and coke formation on Pt/Al2O3 and PtSn/Al2O3 catalysts, Appl. Catal. A 30 (1987) 69-80.

L. Lin, T. Zhang, J. Zang, Z. Xu, Dynamic process of carbon deposition on Pt- and Pt-Sn catalyst for alkane dehydrogenation, Appl. Catal. A 67 (1990) 11-23.

S. B. Kogan, H. Schramm, M. Herskowitz, Dehydrogenation of propane on modified Pt/teta-alumina.Perfprmance in hydrogen and steam environment, Appl. Catal. A 208 (2001) 185-191.

F. J. Rivera-Latas, R. A. Dalla Betta, M. Boudat, Fraction of Pt surface covered with coke following hydrogenolysis of hexane, AIChE Journal 38 (1992) 771-780.

M. Larsson, M. Hulten, E. A. Blekkan, B. Andersson, The effect of reactions and time on stream on the coke formed during propane dehydrogenation, J Catal. 164 (1996) 44-53.

J. Barbier, P. Marecot, N. Martin, L. Elassal, R. Maurel, Catalyst deactivation, Stud, Surf. Sci. vol. 6, B. Delmon and G. E. Froment (Eds),( Amsterdam, Elsevier Sci. Publ. Co,1980, pp.53-62).

S. B. Kogan, N. M. Podkletnova, A. S. Ilyasova, N. R. Bursian, Investigation of coke deposition on platinized catalysts by means of differential thermal analysis, J.Appl.Chem. USSR, 56 (1983) 1710-1713.

J. M. Parera, M. S. Figoli, E. M. Traffano, J. N. Beltramini, E. E. Martinelli, The influence of coke deposition on the fuction of Pt/Al2O3-Cl bifunctional catalyst, Appl. Catal. A 5 (1983) 33-41.

J. Beltramini, D. L. Trimm, Catalytic reforming of n-heptane on platinum, tin and platinum-tin supported on alumina, Appl. Chem., 31(1987) 113-118.

J. M. Parera, J. N. Beltramini, Stability of bimetallic reforming catalysts, J Catal., 112 (1988) 357-365.

S. Bhatia, J. Beltramini, D. D. Do, Temperature programmed analysis and its application in catalytic systems, Catal. Today 7 (1990) 309-348.

S. M. Stagg, C. A. Querini, W. E. Alvarez, D. E. Resasco, Isobutane dehydrogenation on Pt-Sn/SiO2 catalysts. .Effect of preparation variables and regeneration treatment, J. Catal. 168 (1997) 75-94.

P. Praserthdam, N. Grisdanurak, W. Yuangsawatdikul, Coke formation over Pt-Sn-K/Al2O3 in C3,C5-C8 alkane dehydrogenation, Chem. Eng. J. 77 (2000) 215-219.

T. S. Basso, Z. Zhang W. M. H. Sachtler, Characterization by pulsed oxidation of coke on platinum/alumina, Appl. Catal. A 79 (1991) 227-240.

S. B. Kogan, I. V. Gorodetskaya, N. M. Podkletnova, G. I. Tysovsky, N. R. Bursian, ESR study of coked platinum catalysts used for dehydrogenation of paraffin hydrocarbons J. Appl. Chem. USSR, 12 (1987) 2655-2659.

A. Palazov, Ch. Bonev, D. Shopov, G. Lietz, A. Arkany, J. Voelter , Adsorption and hydrogenation of ethylene, 1-hexene, and benzene and CO adsorption on PtAl2O3 and PtSnAl2O3 catalysts, J. Catal. 103 (1987) 249-260.

F. Passos, M. Schmal, M. A. Vannice, Ethylene adsorption on Al2O3 supported Pt, Pt-Sn and Pt-In catalysts, J. Catal. 160 (1996) 118 -124.

C. Panja, N. A. Saliba, B. E. Koel, Coking resistance of Pt-Sn alloys probed by acetylene chemisorptions, Catal. Lett. 68 (2000) 175-180.

S. A. Bocanegra, A. Guerrero-Ruiz, S. R. de Miguel, O. A. Scelza, Performance of PtSn catalysts supported on MAl2O4 (M: Mg or Zn) in n-butane dehydrogenation : characterization of the metallic phase, Appl. Catal. A 277 (2004) 11-22.

L. K. Lok, N. A. Gaidai, S. L. Kiperman, N. M. Podkletnova, S. B. Kogan, Investigation of the kinetics of side reactions in the ehydrogenation of isobutane and the kinetics of the main reaction under transient conditions on platinum catalysts, Kinet. Catal. 29 (1988) 989-996.

M. Hansen, Constitution of Binary Alloys (2-nd ed. McGrill-Hill Book Co., New York, 1958, pp.348-378).

A. E. Vol, Handbook of Binary Metallic Systems ( Israel Program for Scientific Translation ,trans. from Russian, 1967, vol. 2, p. 85).

J. Margitfalvi, S. Goeboeloes, E. Kwaysser, M. Hegedus, F. Nagi, L. Koltai, Role of rhenium in bimetallic reforming catalysts, React. Kinet. Catal. Lett. 24 (1984) 315-321.

J. M. Parera, C. A. Querini, J. N. Beltramini, N. S. Figoli, Activity, selectivity and stability of bimetallic catalysts in n- paraffin and cyclopentane reforming, Appl. Catal. A 32 (1987) 117-132.

J. M. Parera, J. N. Beltramini, C. A. Querini, E. E. Martinelli, E. J. Churin, P. E. Aloe, N. S. Figoli, The role of Re and S in the Pt-Re -S/Al2O3 catalyst, J. Catal. 99 (1986) 39-52.

J. M. Parera, J. N. Beltramini, Stability of bimetallic reforming catalysts, J. Catal. 112 (1988) 357-365.

V. K. Shum, J. B. Butt, W. M. H. Sachtler, The effect of rhenium and sulfur on the activity maintenance and selectivity of platinum/alumina hydrocarbon conversion catalysts, J. Catal. 96 (1985) 371-380.

V. K. Shum, J. B. Butt, W. M. H. Sachtler, The effect of rhenium and sulfur on the activity maintenance and selectivity of platinum/alumina hydrocarbon conversion catalysts, J. Catal. 99 (1986) 126-139.

A. Borgna, T. F. Garetto, R. Apestigua, Simultaneous deactivation by coke and sulfur of bimetallic Pt-Re(Ge,Sn)/Al2O3 catalysts for n-hexane reforming, Appl.Catal. A 197 (2000) 11-21.

E. A. Timofeeva, A.P. Tyupaev, G. V. Isagulyantz,,Effect of adding rhenium to alumina-platinum catalysts for dehydrogenation the higher paraffins, Russian chemical bulletin 1(1982) 2347-2350.

N. R. Bursian, S. B. Kogan, Effect of rhenium in dehydrogenation of n-dodecane on platinum catalyst, Prepr. Problemy desaktivazii katalizatorov (Russ.) (CO AН CCCР, Новосибирск,1990) pp.14-34.

C. L. Pieck, P. Marecot, C. A. Querini, J. M. Parera, J. Barbier, Influence of Pt-Re interaction on activity and selectivity of reforming catalysts, Appl. Catal. A 133 (1995)281-292.

F. H. Ribeiro, A. L. Bonivardi, C. Kim, G. A. Samorjai, Transformation of platinum into a stable , high-temperature dehydrogenation-hydrogenation catalyst by ensemble size reduction with rhenium and sulfur, J. Catal.150 (1994) 186-198

P. Biloen, J. N. Helle, H. Verbeek, F. M. Dautzenberg, W. M. H. Sachtler, The role of rhenium and sulfur in platinum based hydrocarbon conversion, J. Catal.63 (1980) 112-118.

V. Ponec, Alloy catalyst: the concepts, Appl. Catal. A 222 (2001) 31-45.

T. Fujikawa, F. H. Ribeiro, G. A. Samorjai, The effect of Sn on the reactions of n-hexane and cyclohexane over polycrystalline Pt foils, J. Catal. 178 (1998) 58-65.

J. H. Sinfelt, Supported "bimetallic cluster" catalysts, J. Catal. 29 (1973) 308-315.

J. H. Sinfelt, Bimetallic Catalysts. Discoveries, Concepts, and Applications (J. Wiley&Sons, New York ,1983, pp.33, 53-59).

J. Phillips, Microcalorimetric studies of the structure of supported bimetallic catalyst particles, J. Thermal. Anal. 49 (1997) 541-552.

J. Phillips, J. Weigle, M. Hershkowitz, S. Kogan, Metal particle structure:contrasting the influenced of carbons and refractory oxides, Appl. Catal. A 173 (1998) 273-287.

D. Bazin, Solid State Concepts to Understand Catalysis Using Nanoscale Metallic Particles, Topics in Catal. 18 (2002) 79-84.

B. A. Sexton, A. E. Hughes, K. Foger, An X-ray photoelectron spectroscopy and reaction study of Pt-Sn catalysts, J. Catal. 88 (1994) 466-477.

R. D. Cortright, J. A. Dumestic, Effects of potassium on silica- supported Pt and Pt/Sn catalysts for isobutane dehydrogenation, J. Catal. 157 (1995) 576-583.

N. A. Sokolova, A. P. Barkova, D. B. Furman, V. Yu. Borovkov, V. B. Kazansky, IR spectroscopic study of the state of Cu and Pt in copper-platinum-alumina catalysts for paraffin dehydrogenation subjected to different reductive and oxidative treatments, Kinet. Catal. 36 (1995) 434-440.

E. L. Jablonski, A. A. Castro, O. A. Scelza, S. R. de Miguel, Effects of Ga addition to Pt/Al2O3 on activity, selectivity and deactivation in propane dehydrogenation, Appl. Catal. A 183 (1999) 189-198.

J. Llorca, N. Homs, J. Leon, J. Sales, J. L. G. Fierro, P. Ramirez de la Piscina, Supported Pt-Sn catalysts highly dispersive for isobutane dehydrogenation: preparation, characterization and catalytic behavior, Appl. Catal. A 189 (1999) 77-86.

Z. Paal, A. Gyory, I. Uszkurat, S. Oliver, M. Guerin, C. Kappenstein, Pt/Al2O3 and Pt-Sn/Al2O3 catalysts prepared by two different methods: hydrogen pressure effects in the reactions of n-hexane, J. Catal.168 (1997) 164-175.

O. Barias, A. Holmen, E. A. Blekkan, Propane dehydrogenation over supported Pt and Pt-Sn catalysts: catalyst preparation, characterization and activity, J. Catal.158 (1996) 1-12.

N. R. Bursian, S. B. Kogan, V. K. Daragan, O. M. Oranskaya, N. M. Podkletnova, Investigation of reactions and catalysts of C3- -C4 paraffins dehydrogenation and aromatization, Prepr. Am.Chem.Soc. Div.Pet.Chem., N.-Y. City Meeting , USA, August 25-30 (1991) vol.36 (4) pp. 738-745.

S. B. Kogan, M. Herskowitz, Geometric and electronic factors in paraffin dehydrogenation on bimetallic platinum catalysts, React.Kinet.Catal.Lett. 85 (2005) 341-345.

F. Passos, M. Schmal, M. A. Vannice, Effect of In and Sn on adsorption behavior and hydrogenolysis activity of Pt/Al2O3 catalysts J. Catal. 160 (1996) 106-117.

T. Komatsu, K. Inaba, T. Uezono, A. Onda, T. Yashima, Nano- -size particles of palladium intermetallic compounds as cata- lyst for oxidative acetoxylation, Appl. Catal. A 251 (2003) 315- -326.

A. Fuercht, A. Tungler, S. Szabo, A. Sarkany, n-Octane reforming over modified catalysts: I the role of Sn,Te and Bi under industrial conditions, Appl. Catal. A 226 (2002) 155-161.

L. K. Lok, N. A. Gaidai, B. S. Gudkov, S. L. Kiperman, S. B. Kogan, Investigation of kinetics and mechanism of the dehydrogenation of isobutane on platinum tin catalyst, ,Kinet. Catal. 27 (1986) 1184-1189.

L. K. Lok, N. A. Gaidai, B. S. Gudkov, M. M. Kostyukovskii, S. L. Kiperman, N. M. Podkletnova, S. B. Kogan, N. R. Bursian, Investigation of the kinrtics and mechanism of the dehydrogenation of isobutane on platinum and platinum-indium catalyst, ,Kinet. Catal. 27 (1986) 1190-1196.

L.K. Lok, N.A. Gaidai, S.L. Kiperman, H.S. Thoang, S.B. Kogan, Kinetics of propane and isobutane dehydrogenation over platinum catalysts in the presence of hydrogen sulfide, Kinet. Catal. 34 (1993) 456-458.

L. K. Lok, N. A. Gaidai, S. L. Kiperman, S. B. Kogan, Kinetics of dehydrogenation of n-butane on platinum catalysts, Kinet. Catal. 31 (1990) 421-424.

L. K. Lok, N. A. Gaidai, S. L. Kiperman, H. S. Thoang, N. M. Podkletnova, S. B. Kogan, Kinetics of propane dehydrogenation on aluminoplatinum catalysts, Kinet. Catal. 32 (1991) 61-66.

N. A. Gaidai, S. K. Mart`yanova, S. L. Kiperman, Mechanism and kinetics of dehydrogenation of higher n-paraffins over promoted platinum catalysts 6. Dehdrogenation of n-decane in the nonsteady state region and coking over a platinum tin catalyst, Kinet. Catal. 33 (1992) 184-188.

N. A. Gaidai, S. K. Mart`yanova, S. L. Kiperman, Mechanism and kinetics of dehydrogenation of higher n-paraffins over promoted platinum catalysts. 7.kinetics of coking during dehydrogenation of n-dodecane and decane-dodecane mixtures over a platinum tin catalyst, Kinet. Catal. 33 (1992) 189-191.

L.K. Lok, N. A. Gaidai, S. L. Kiperman, H. S. Thoang, Kinetics of the dehydrogenation of n-butane and its mixtures with propane over platinum catalysts Kinet. Catal. 34 (1993) 451-455.

L. K. Lok, N. A. Gaidai, S. L. Kiperman, H. S. Thoang, P. B. Novikov, Kinetics of side reactions in dehydrogenation of n-butane over platinum-potassium catalysts, Kinet. Catal. 36 (1995)504-510.

L. K. Lok, N. A. Gaidai, S. L. Kiperman, H. S. Thoang, Kinetics of isopentane dehydrogenation over platinum-potassium catalysts, Kinet. Catal. 36 (1995) 511-516.

L. K. Lok, N. A. Gaidai, S. L. Kiperman, H. S. Thoang, N. M. Podkletnova, V. Yu. Georgievskii, Kinetics of isobutane dehydrogenation over platinum-alumina catalysts in the presence of water vapor, Kinet. Catal. 36 (1995) 517-523.

L. K. Lok, N. A. Gaidai, S. L. Kiperman, H. S. Thoang, Kinetics of isopentane dehydrogenation over platinum-alumina catalysts in the presence of hydrogen and water vapor, Kinet. Catal. 37 (1996) 797-801.

L. K. Lok , N. A. Gaidai, S. L. Kiperman, H. S. Thoang, ,Kinetics of propane and n-butane dehydrogenation over platinum-alumina catalysts in the presence of hydrogen and water vapor, Kinet. Catal. 37 (1996)790-796.

S. L. Kiperman, N. A. Gaidai, Kinetic and mechanistic studies of steady-state and non-steady-state heterogeneous catalytic reactions, Kinet.Catal. 40 (1999) 638-652.

N. A. Gaidai, S. L. Kiperman, Kinetic models of catalyst deactivation in paraffin dehydrogenation, Kinet. Catal. 42 (2001) 527 -532.

R. D. Cortright, J. A. Dumesic, L-zeolite supported platinum and platinum/tin catalysts for isobutane dehydrogenation, Appl. Catal. A 129(1995)101-115.

R. D. Cortright, P. E. Levin, J. A. Dumesic, Kinetic studies of isobutane and isobutene hydrogenation over Pt/Sn-based catalysts, Ind. Eng. Chem. Res. 37 (1998) 1717-1723.

M. J. Hill, R. D. Cortright, J. A. Dumesic, Silica and L-zeolite supported Pt, Pt/Sn and Pt/Sn/K catalysts for isobutane dehydrogenation, Appl. Catal. A 168 (1998) 9-21.

R. D. Cortright, M. J. Hill, J. A. Dumesic, Selective dehydrogenation of isobutane over supported Pt/Sn catalysts, Catal. Today 55 (2000) 213-223.

N. M. Podkletnova, S. B. Kogan, N. R. Bursian, Activity and stability of bimetallic catalysts in dehydrogenation of n-dodecane, J. Appl. Chem. USSR 60 (1987) 1872-1875.

T. Imai, D.-Y. Jan, Catalytic oxidative steam dehydrogenation process, US pat. 4,778,371, UOP Inc. (1998).

J. Bricker, D.-Y. Jan, J. M. Foresman, Dehydrogenation catalyst composition, US pat. 4,914,075, UOP (1990). .

D. Akportiaye, S. F. Jensen, U. Olsboy, F. Rohr, E. Rytter, M. Roennekleiv, A. J. Spjelkavik, Ethane dehydrogenation on Pt/Mg(Al)O and PtSn/Mg(Al)O catalysts, ,Ind. Eng. Chem. Res. 40 (2001) 4741-4748.

S. B. Kogan, M. Herskowitz, Selective propane dehydrogenation to propylene on novel bimetallic catalysts,Catal. Commun. 2 (2001) 179-185.

S. B. Kogan, M. Herskowitz, Oxygen promoted conversion of light alkanes to olefins on polymetallic platinum catalysts, 4-th World Cong. Oxidative Catal ( Berlin/Potsdam,Germany, September 6-21, 2001, vol. 2, pp. 231-325).

S. B. Kogan, M. Herskowitz, Catalyst for converting paraffinic hydrocarbons into corresponding olefins, US patent 6,414,209 (2002).

R. K. Grasselli, D. L. Stern, J. G. Tsikoyiannis, Catalytic dehydrogenation (DH) of light paraffins combined with selective hydrogen combustion (SHC): I. DH, SHC, DH catalysts in series (co-fed process mode), Appl. Catal. A 189 (1999) 1-8.

M. P. Atkins, G. R. Evans, A review of current processes and innovations in catalytic dehydrogenation, Erdoel, Erdgas, Kohle, 111(1995) 271-274.

S. Kaskel, K. Schlichte, Porous superbase nitride as a superbase catalyst, J. Catal. 201 (2001) 270-274.

M. A. Centeno, M. Debois, P. Grande, Platinum aluminophosphate oxynitride (Pt-AlPON) catalyst for the dehydrogenation of isobutane to isobutene,,J. Catal. 192 (2000) 296-306.

D. Hullmann, G. Wendt, U. Singlair, G. Ziegenbalg, Propane dehydrogenation over supported platinum silicon nitride catalysts, Appl. Catal. A 225 (2002) 261-270.

P. Forzatti , L. Lietti, Catalyst deactivation, Catal. Today 52 (1999) 165-181.

S. C. Fung, Redispersion of iridium using in situ chlorine generation and avoiding iron contamination, Catal. Today, 53 (1999) 325-338.

G. Meitzner, G. H. Via, F. W. Lytle, S. C. Fung, J. H. Sinfelt, Extended x-ray adsorption fine structure (EXAFS) studies of platinum-tin catalysts, J. Phys. Chem. 92 (1998) 2925-2932.

R. Srinivasan, B. H. Davis,The structure of platinum-tin reforming catalysts, Platinum metals rev. 36 (1992) 151-163.

M. Huff, L. D. Schmidt, Oxidative dehydrogenation of isobutane over monoliths at short contact times, J. Catal. 155 (1995) 82-94.

L. S. Liebermann, L. D. Schmidt, Oxidative dehydrogenation of isobutane at short contact times, Appl. Catal. A 179 (1999) 93-106.

A. S. Bodke, D. A. Olschki, L. D. Schmidt, E. Ranzi, High selectivities to ethylene by partial oxidation of ethane, Science 285 (1999) 712-720.


Refbacks

  • There are currently no refbacks.



Please send any question about this web site to info@praiseworthyprize.com
Copyright © 2005-2024 Praise Worthy Prize