Adsorption of Meropenem Antibiotics from Aqueous Solutions on Multi-Walled Carbon Nanotube
Pharmaceutical-instigated pollution is a major concern, especially in relation to aquatic environments and drugs such as meropenem antibiotics. Adsorbents, such as multi-walled carbon nanotubes, offer potential as means of removing polluting meropenem antibiotics and other similar compounds from water. In order to evaluate the effectiveness of multi-walled carbon nanotubes in this capacity, various experimental parameters, including contact time, initial concentration, pH, temperature and the dose of adsorbent have been investigated. The Langmuir and the Freundlich isotherm models have been used. The data obtained using a modified Langmuir model have been consistent with the experimental ones; the best pH value has been obtained to have the maximum uptake capacity with the hights coefficient of determination. The adsorption kinetics data is in accordance with pseudo-second order model for adsorption processes, which is in line with the measured data. The results of this thermodynamic research indicate that the reaction that removes meropenem antibiotics from water by adsorption is exothermic. A combination of mechanisms is responsible for meropenem antibiotics adsorption to adsorbent, including electrostatic and π–π EDA interactions, hydrophobic interaction, functional groups and molecule substitution. According to the research findings, multi-walled carbon nanotubes offer a potential method that can be quickly deployed in order to address pharmaceutical contamination of water.
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Akchurin, T., Stefanenko, I., Pushkarskaya, O., Slag Wastes from Regional Metallurgical Industry Used in Construction Compositions, (2017) International Review of Civil Engineering (IRECE), 8 (5), pp. 197-202.
I. Ahmed, M. Gasser, Adsorption Study of Anionic Reactive Dye from Aqueous Solution to Mg–Fe–CO3 Layered Double Hydroxide (LDH), Appl. Surf. Sci., Vol. 259:650-656, 2012.
G. Zhang, J. Yina, J. Zhao, H. Zhu, C. Wang, Adsorption and removal of tetracycline from water by petroleum coke-derived highly porous activated carbon, J Envir Chem Eng., Vol.3:1504-12, 2015.
H. A. Abdel-Gawwad, K.A. Khalil, Application of thermal treatment on cement kiln dust and feldspar to create one-part geopolymer cement, Construction and Building Materials, Vol.187: 231-237, October 2018.
M. Akram, H. Bhatti, M. Iqbal, S. Noreen, S. Sadaf, Biocomposite efficiency for Cr(VI) adsorption: Kinetic, equilibrium and thermodynamics studies, J Environ Chem Eng., Vol.5:400-, 2017.
Miloudi, M., Merbouh, M., Glaoui, B., Mechanical Properties of Concrete Using Coal Waste (Heap) as Partial Replacements of Fine Aggregate in Hot Weather, (2017) International Review of Civil Engineering (IRECE), 8 (4), pp. 120-124.
L. Ai, J. Jiang, Removal of methylene blue from aqueous solution with self-assembled cylindrical graphene–carbon nanotube hybrid, Chem Eng J. Vol.192:156-63, 2012.
Y. Ho, J. Porter, G. McKay, Equilibrium isotherm studies for the sorption of divalent metal ions onto peat: Copper, nickel and lead single component systems, Water Air Soil Pollut. Vol. 141:1-33, 2002.
M. Ahmed, J. Zhou, H. Ngo, W. Guo, Adsorptive removal of antibiotics from water and wastewater: Progress and challenges, Sci Total Environ. Vol.532:112-26, 2008.
A. Sulaymon, S. Ebrahim, M. M-Ridha, Equilibrium, kinetic, and thermodynamic biosorption of Pb(II), Cr(III), and Cd(II) ions by dead anaerobic biomass from synthetic wastewater, Environmental Science and Pollution Research, Vol.20:175-87, 2013.
W. Davis, C. Erickson, C. Johnston, J. Delfino, J. Porter, Quantitative fourier transform infrared spectroscopic investigation humic substance functional group composition, Chemosphere. Vol.38:2913-28, 1999.
P. Zhao, F. Yu, R. Wang, Y. Ma, Y. Wu, Sodium alginate/graphene oxide hydrogel beads as permeable reactive barrier material for the remediation of ciprofloxacin-contaminated groundwater, Chemosphere, Vol. 200:612-620, 2018.
A. Boxall, D. Kolpin, B. Sørensen, J. Tolls, Peer reviewed: are veterinary medicines causing environmental risks? Environ Sci Technol. Vol. 37:286A-94A, 2003.
M. M-Ridha, M. Abdul-Ahad, Adsorption of Levofloxacine antibacterial from contaminated water by non – conventional low cost natural waste materials, Journal of Engineering, Vol. 20:88-104, 2014.
N. Chakrapani, Y. Zhang, S. Nayak, Chemisorption of acetone on carbon nanotubes. J Phys Chem B. Vol. 107:9308-11, 2003.
A. Ahmed, M. M-Ridha, N. Raoof Kinetic, thermodynamics, and equilibrium biosorption of Pb(II), Cu(II) and Ni(II) using dead mushroom biomass under batch experiment, Bioremediation Journal, Vol.20:252-61, 2016.
R. Dantas, S. Contreras, C. Sans, S. Esplugas, Sulfamethoxazole abatement by means of ozonation. J Hazard Mater., Vol.150:790-94, 2008.
M. Keiluweit, M. Kleber, Molecular-Level interactions in soils and sediments: the role of aromatic π-systems, Environ Sci Technol. Vol.43:3421-29, 2009.
H. A. Abdel-Gawwad, K. A. and Khalil, Application of thermal treatment on cement kiln dust and feldspar to create one-part geopolymer cement, Construction and Building Materials, Vol.187: 231-237, October 2018.
R. Han, L. Zou, X. Zhao, Y. Xu, F. Xu, Y. Li, Y. Wang, Characterization and Properties of Iron Oxide-Coated Zeolite as Adsorbent for Removal of Copper (II) from Solution in Fixed Bed Column, Chem. Eng. J., Vol. 149:123-131, 2009.
W. Chen, L. Duan, L. Wang, D. Zhu, Adsorption of Hydroxyl- and Amino-Substituted Aromatics to Carbon Nanotubes, Environ Sci Technol., Vol. 42:6862-68, 2008
H. Fu, X. Li, J. Wang, Activated carbon adsorption of quinolone antibiotics in water: Performance, mechanism, and modeling. J. Environ. Sci., Vol.56:145-52, 2017.
A. Daifullah, B Girgis, Impact of surface characteristics of activated carbon on adsorption of BTEX, Colloids Surfaces A Physicochem Eng Aspl. Vol.214:181-93, 2003.
D. Grover, J. Zhou, P. Frickers, J. Readman, Improved removal of estrogenic and pharmaceutical compounds in sewage effluent by full scale granular activated carbon: Impact on receiving river water. J Hazard Mater. Vol.185:1005-1, 2011.
M. Turk Sekulic, N. Boskovic, A. Slavkovic, J. Garunovic, S. Kolakovic, S. Pap, Surface functionalised adsorbent for emerging pharmaceutical removal: Adsorption performance and mechanisms. Process Saf. Environ. Prot., Vol. 125:50-63, 2019.
M. Ali, M. M-Ridha, M Taly, Optimization kerosene bio-degradation by a local soil bacterium isolate Klebsiella Pneumoniae sp. Pneumonia. J Pure Appl Microbiol., Vol.12:2049-57, 2018.
K. Kümmerer, The presence of pharmaceuticals in the environment due to human use – present knowledge and future challenges. J Environ Manage. Vol.90:2354-66, 2009.
N. Tran, H. Chen, M. Reinhard, Occurrence and removal of multiple classes of antibiotics and antimicrobial agents in biological wastewater treatment processes. Water Res. Vol.104:461-72, 2006.
W. Wu, W. Jiang, W. Xia, Influence of pH and surface oxygen-containing groups on multiwalled carbon nanotubes on the transformation and adsorption of 1-naphthol, J Colloid Interface Sci. Vol.374:226-31, 2012.
H. Peng, B. Pan, M. Wu, Adsorption of ofloxacin on carbon nanotubes: Solubility, pH and cosolvent effects, J Hazard Mater Vol.211-212:342-48, 2012.
L. Zhou, L. Ji, P. Ma, Development of carbon nanotubes/CoFe2O4 magnetic hybrid material for removal of tetrabromobisphenol A and Pb(II), J Hazard Mater, Vol.265:104-14, 2014.
J. Wang, and S. Wang, Removal of pharmaceuticals and personal care products (PPCPs) from wastewater: A review. J. Environ. Manage. Vol. 182:620-640, 2016.
Y. Wang, C. Shen, M. Zhang, B. Zhang, Y. Yu, The electrochemical degradation of ciprofloxacin using a SnO2-Sb/Ti anode: Influencing factors, reaction pathways and energy demand. Chem. Eng. J., 296:79-89, 2016.
E. Szekeres, A. Baricz, C. Chiriac, Abundance of antibiotics, antibiotic resistance genes and bacterial community composition in wastewater effluents from different Romanian hospitals, Environ Pollut. Vol.225:304-15, 2017.
H. Zhao, X. Liu, Z. Cao, Adsorption behavior and mechanism of chloramphenicols, sulfonamides, and non-antibiotic pharmaceuticals on multi-walled carbon nanotubes, J Hazard Mater. Vol.310:235-45, 2016.
N. Cai, P. Larese-Casanova, Sorption of carbamazepine by commercial graphene oxides: A comparative study with granular activated carbon and multiwalled carbon nanotubes, J Colloid Interface Sci., Vol.426:152-61, 2014.
D. Zhang, B. Pan, M. Wu, Adsorption of sulfamethoxazole on functionalized carbon nanotubes as affected by cations and anions, Environ Pollut. Vol.159:2616-21, 2011.
Muslim, A., Marwan, M., Saifullah, R., Azwar, M., Darmadi, D., Putra, B., Rizal, S., Adsorption of Cu(II) Ions on Areca Catechu Stem-Based Activated Carbon: Optimization Using Response Surface Methodology, (2019) International Review on Modelling and Simulations (IREMOS), 12 (2), pp. 123-129.
Chaves, L., Guerra, H., de B. Chaves, I., Zinc Adsorption and its Thermodynamic Parameters in Cambisols, (2017) International Review of Physics (IREPHY), 11 (6), pp. 181-185.
Sabbar, J., Gueraoui, K., Taibi, M., Men-La-Yakhaf, S., Ouhimmou, S., Numerical Solution of the Pollutant’s Penetration in a Specific Soil in Tensift (South Morocco), (2019) International Review of Mechanical Engineering (IREME), 13 (7), pp. 390-401.
Al-Sultan, A., Al-Wakel, S., Al-Taie, A., Experimental Study of Heavy Metal Dispersion through Cohesionless Soil: a Case Study of Cd+, (2019) International Review of Civil Engineering (IRECE), 10 (6), pp. 288-293.
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