Open Access Open Access  Restricted Access Subscription or Fee Access

Research of Pyrolitic Charring Mechanism in Natural and Fire Retardant Treated Pine Wood


(*) Corresponding author


Authors' affiliations


DOI: https://doi.org/10.15866/irece.v5i6.4420

Abstract


There is a number of various fire retardant solutions created worldwide, however, performance research has not been carried out in detail for all of them. Furthermore, the process of wood combustion and charring is further impeded by different environmental conditions forming during fire. The work covers the thermogravimetric, microscopic and EDS research in different environmental conditions. Based on the thermogravimetric research it was determined that there had been three exo-effects recorded in the DTA curve for natural pine in the air medium, whereas for natural pine wood in the nitrogen medium and natural pine treated with BAK-1 both in the air and nitrogen media there had been six exo-effects recorded. Based on the EDS research it was determined that in the residue of both, natural and treated pine produced in the nitrogen environment, the amount of oxygen had been lower and the amount of carbon had been higher compared to the residue produced in the air environment, which means that processes in the nitrogen environment take place using the oxygen present in the wood composition, and oxidation of char in the air medium takes place in a more intensive manner. This is partially confirmed by the microscopic (SEM) research of the pine char residue.
Copyright © 2014 Praise Worthy Prize - All rights reserved.

Keywords


Wood; Fire Retardants; Thermogravimetric Analysis; SEM; EDS

Full Text:

PDF


References


Č. Jakimavičius, Timber study (Technologija, 2003).

B. Östman, A. Voss, A. Hughes, P. J. Hovde, O. Grexa, Durability of fire retardant treated wood at humid and exterior conditions. Review of literature, Fire and Materials, Vol. 25(Issue 3): 95–104, 2001.
http://dx.doi.org/10.1002/fam.758

S. L. Levan, J. E. Winandy, Effects of fire-retardant treatments on wood strength: A review, Wood and Fiber Science Vol. 22 (Issue 1): 113–131, 1990.

Z. Karpovič, R. Šukys, R. Gudelis, Toxicity research of smouldering and flaming pine timber treated with fire retardant solutions, Journal of Civil Engineering and Management, Vol. 18(Issue 4): 600–608, 2012.
http://dx.doi.org/10.3846/13923730.2012.709195

K. T. Subyakto, T. Hata, S. Ishihara, S. Kawai, H. Getto, 1998. Improving fire retardancy of fast growing wood by coating with fire retardant and surface densification, Fire mater, Vol. 22(Issue 5):207–212, 1998.
http://dx.doi.org/10.1002/(sici)1099-1018(199809/10)22:5%3C207::aid-fam654%3E3.0.co;2-s

R. Stevens, S. Daan, R. Bezemer, A. Kranenbarg, The structure – activity relationship of fire retardant phosphorus compounds in wood, Polymer degradation and stability. Elsevier: 832–841, 2006.
http://dx.doi.org/10.1016/j.polymdegradstab.2005.06.014

H. A. Lecomte, J J. Liggat, Commercial fire-retarded PET formulations e Relationship between thermal degradation behaviour and fire-retardant action, Polymer Degradation and Stability, Vol. 93: 498–506, 2008.
http://dx.doi.org/10.1016/j.polymdegradstab.2007.11.005

C. S. Chou, S. H. Lin, C. I. Wang, Preparation and characterization of the intumescent fire retardant coating with a new flame retardant, Advanced Powder Technology, Vol. 20(Issue 2): 169–176, 2009.
http://dx.doi.org/10.1016/j.apt.2008.07.002

M. Hagen, J. Hereid, M. A. Delichatsios, J. Zhang, D. Bakirtzis, Flammability assessment of fire-retarded Nordic Spruce wood using thermogravimetric analyses and conecalorimetry, Fire Safety Journal, Vol. 44: 1053–1066, 2009.
http://dx.doi.org/10.1016/j.firesaf.2009.07.004

R. Mačiulaitis, V. Praniauskas, Fire tests on wood products subjected to different heat fluxes, Journal of Civil Engineering and Management, Vol. 16(Issue 4): 484–490, 2010.
http://dx.doi.org/10.3846/jcem.2010.54

M. Grigonis, R. Mačiulaitis, V. Praniauskas, Ageing of Fire Coatings, (2012) International Review of Civil Engineering (IRECE), 3 (1), pp. 71-78.

R. Mačiulaitis, V. Praniauskas, G. Yakovlev, Research into the fire properties of wood products most frequently used in construction, Journal of Civil Engineering and Management, Vol. 19(Issue 4): 573–582, 2013.
http://dx.doi.org/10.3846/13923730.2013.810169

sons, 1998).&D. Drysdale, An introduction to fire dynamics. Second edition. (John wiley

Q. Wu, B. Qu, Synergistic effects of silicotungistic acid on intumescent flameretardant polypropylene, Polymer Degradation and Stability, Vol. 74(Issue 2): 225–261, 2001.
http://dx.doi.org/10.1016/s0141-3910(01)00155-0

S. Liodakis, D. Bakirtzis, E. Lois, D. Gakis, The effect of (NH4)2HPO4 and (NH4)2SO4 on the spontaneous ignition properties of Pinus halepensis pine needles, Fire Safety Journal, Vol. 37(Issue 5): 481–494, 2002.
http://dx.doi.org/10.1016/s0379-7112(02)00008-5

A. Agueda, E. Pastor, E. Planas, Different scales for studying the effectiveness of long-term forest fire retardants, Progress in Energy and Combustion Science Journal, Vol. 34(Issue 6): 782–796, 2008.
http://dx.doi.org/10.1016/j.pecs.2008.06.001

A. M. Pereyra, C. A. Giudice, Flame-retardant impregnants for woods based on alkaline silicates, Fire Safety Journal, Vol. 44(Issue 4): 497–503, 2009.
http://dx.doi.org/10.1016/j.firesaf.2008.10.004

M. A. Hassan, R. Kozlowski, B. Obidzinski, New Fire-Protective Intumescent Coatings for Wood, Journal of Applied Polymer Science, Vol. 110(Issue 1): 83–90, 2008.
http://dx.doi.org/10.1002/app.28518

T. T. Fu, Q. M. Xiao, F. Chao, Investigation on combustion of fire retardant board under different N2–O2 mixture gas atmospheres by using thermogravimetric analysis, Construction and Building Materials, Vol. 25: 2076–2084, 2011.
http://dx.doi.org/10.1016/j.conbuildmat.2010.11.036

Y. Zhaosheng, M. Xiaoqian, L. Ao, Thermogravimetric analysis of rice and wheat straw catalytic combustion in air- and oxygen-enriched atmospheres, Energy Conversion and Management, Vol. 50: 561–566, 2009.
http://dx.doi.org/10.1016/j.enconman.2008.10.022

R. Mačiulaitis, A. Jefimovas, P. Zdanevičius, Research of natural wood combustion and charring processes, Journal of Civil Engineering and Management, Vol. 18(Issue 5): 631–641, 2012.
http://dx.doi.org/10.3846/13923730.2012.720935

LST EN 13238:2010 Reaction to fire tests for building products - Conditioning procedures and general rules for selection of substrates, CEN, 2010, 11 p.
http://dx.doi.org/10.3403/30166839

V. Gurskienė, A. Šlančiauskas, Acceleration of gasification of residual wood char by enhancing CO2 gas generation, Energetika, Vol. 58(Issue 4): 213–218, 2012.


Refbacks

  • There are currently no refbacks.



Please send any question about this web site to info@praiseworthyprize.com
Copyright © 2005-2024 Praise Worthy Prize