Mapping Surface Heterogeneity: the AFM-Based Approach


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Abstract


In this short review, the use of maps is presented charting the surface distribution of the forces of adhesion, indentation and friction, as obtained with the atomic force microscope for the study of surface homogeneity. Phase-separated polymer blends are chosen as examples to demonstrate the complementarity of the method with the more usual topographical imaging approach. Consequent to recent advances towards the determination of surface energy at the sub-micrometre scale, the mapping of this property is now a realistic possibility
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Keywords


Atomic Force Microscopy; Force-of-Adhesion Mapping; Indentation Mapping; Friction-Coefficient Mapping; Surface-Energy Mapping

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References


A. Kawai, H. Nagata, H. Morimoto, M. Takata, M, In Surface Modification Technologies VII, Proc. 7th Int. Conf., T.S. Sudarshan, K. Ishizaki, M. Takata, K. Kamata (Eds.), Sanjo, Niigata, Japan, 31 Oct−2 Nov 1993.

A. Kawai, H. Nagata, M. Takata, Characterization of Surface Energetic Behavior by Atomic Force Microscopy, Japanese Journal of Applied Physics, Volume 31, 1992, Pages L977-L979.

J. Tsibouklis, P. Graham, P.J. Eaton, J.R. Smith, T.G. Nevell, J.D. Smart, R.J. Ewen, Poly(perfluoroalkyl methacrylate) film structures: Surface organization phenomena, surface energy determinations, and force of adhesion measurements, Macromolecules, Volume 33, 2000, Pages 8460-8465.

B. Capella, P. Baschieri, C. Frediani, P. Miccoli, C. Ascoli, Improvements in AFM Imaging of the Spatial Variation of Force - Distance Curves: On-Line Images, Nanotechnology, Volume 8, 1997, Pages 82-87.

B. Capella, G. Dietler, Force-Distance Curves by Atomic Force Microscopy, Surface Science Reports, Volume 34, 1999, Pages 1-104.

T. Ishino, H. Hieda, K. Tanaka, N. Gemma, Imaging Charged Functional Groups with an Atomic Force Microscope Operated in Aqueous Solutions, Journal of Electroanalytical Chemistry, Volume 438, 1997, Pages 225-230.

P.J. Eaton, P. Graham, J.R. Smith, J.D. Smart, T.G. Nevell, J. Tsibouklis, Mapping the Surface Heterogeneity of a Polymer Blend: An Adhesion-Force-Distribution Study Using the Atomic Force Microscope, Langmuir, Volume 16, 2000, Pages 7887-7890.

T. Abbis, G. Collins, Force Mapping using Layered Imaging Offers Numerous Benefits to Users, R&D Magazine, Volume 3 1995, Pages 57-58.

S. Zhu, Y. Liu, M.H. Rafailovich, J. Sokolov, D. Gersappe, D.A. Winesett, H. Ade, Confinement-Induced Miscibility in Polymer Blends, Nature, Volume 400, 1999, Pages 49-51.

D. Glennon, J.R. Smith, P.A. Cox, R.J. Ewen, R.T. Nevell, T.G. Nevell, J. Tsibouklis, Molecular Organization in Structural PVDF, Journal of Materials Science, Volume 33, 1998, Pages 3511-3517.

G. Binnig, C. Quate, F.C. Gerber, Atomic Force Microscope, Physics Review Letters, Volume 56, 1986, Pages 930-933.

H.A. Mizes, K.G. Loh, R.J.D. Miller, S.K. Ahuja, E.F. Grabowski, Submicron Probe of Polymer Adhesion with Atomic Force Microscopy - Dependence on Topography and Material Inhomogeneities, Applied Physics Letters, Volume 59, 1991, Pages 2901-2903.

H.-U. Krotil, T. Stifter, O. Marti, Combined Dynamic Adhesion and Friction Measurement with the Scanning Force Microscope, Applied Physics Letters, Volume 77, 2000, Pages 3857-3859.

P. Eaton, E.F. Estarlich, R.J. Ewen, T.G. Nevell, J.R. Smith, J. Tsibouklis, Combined Nanoindentation and Adhesion Force Mapping using the Atomic Force Microscope: Investigations of a Filled Polysiloxane Coating, Langmuir, Volume 18, 2002, Pages 10011-10015.

A.L. Weisenhorn, P. Maivald, H.J. Butt, P.K. Hansma, Measuring Adhesion, Attraction, and Repulsion Between Surfaces in Liquids with an Atomic-Force Microscope, Physics Reviews B-Condensed Matter, Volume 45, 1992, Pages 11226-11232.

B.D. Beake, N.J. Brewer, G.J. Leggett, Scanning Force Microscopy of Polyester: Surface Structure and Adhesive Properties, Macromolecular Symposia, Volume 167, 2001, Pages 101-115.

N.A. Burnham, R.J.J. Colton, Measuring the Nanomechanical Properties and Surface Forces of Materials Using an Atomic Force Microscope, Journal of Vacuum Science and Technology A, Volume 7, 1989, 2906-2913.

D. Raghavan, X. Gu, T. Nguyen, M. VanLandingham, A. Karim, Mapping Polymer Heterogeneity using Atomic Force Microscopy Phase Imaging and Nanoscale Indentation, Macromolecules, Volume 33, 2000, Pages 2573-2583.

W. Xu, P.J. Mulhern, B.L. Blackford, M.H. Jericho, I.A. Templeton, A New Atomic-Force Microscopy Technique for the Measurement of the Elastic Properties of Biological-Materials, Scanning Microscopy, Volume 8, 1994, Pages 499-506.

A. Vinckier, G. Semenza, Measuring Elasticity of Biological Materials by Atomic Force Microscopy, FEBS Letters, Volume 430, 1998, Pages 12-16.

D.R. Baselt, J.D. Baldeschwieler, Lateral Forces during Atomic Force Microscopy of Graphite in Air, Journal of Vacuum Science and Technology B, Volume 10, 1992, Pages 2316-2322.

C. Polaczyk, T. Schneider, J. Schöfer, E. Santner, Microtribological Behavior of Au(001) Studied by AFM/FFM, Surface Science, Volume 402-404, 1998, Pages 454-458.

E. Barrena, C. Ocal, M.A. Salmeron, Comparative AFM Study of The Structural and Frictional Properties of Mixed and Single Component Films of Alkanethiols on Au(111), Surface Science, Volume 482, 2001, Pages 1216-1221.

X. Liu, D.G. Chetwynd, J.W. Gardner, P.N. Bartlett, C. Beriet, Measurements of Tribological Properties of Poly(Pyrrole) Thin Film Bearings, Tribology International, Volume 31, 1998, Pages 313-323.

M.D. Levi, Y. Cohen, D. Aurbach, M. Lapkowski, E. Vieil, J. Serose, Atomic Force Microscopy Study of the Morphology of Polythiophene Films Grafted onto the Surface of a Pt Microelectrode Array, Synthetic Metals, Volume 109, 2000, Pages 55-65.

F.Z. Sidouni, N. Nurdin, P. Chabrecek, D. Lohmann, J. Vogt, N. Xanthopoulos, H. Mathieu, P. Francois, P. Vandaux, P. Descouts, Surface Properties of a Specifically Modified High-grade Medical Polyurethane, Surface Science, Volume 491, 2001, Pages 355-369.

J.R. Smith, J.A. Swift, Lamellar Subcomponents of the Cuticular Cell Membrane Complex of Mammalian Keratin Fibres Show Friction and Hardness Contrast by AFM, Journal of Microscopy, Volume 206, 2002, Pages 182-193.

G. Bogdanovic, A. Meurk, M.W. Rutland, Tip Friction - Torsional Spring Constant Determination, Colloids and Surfaces B-Biointerfaces, Volume 19, 2000, Pages 397-405.

D.F. Ogletree, R.W. Carpick, M. Salmeron, Calibration of Frictional Forces in Atomic Force Microscopy, Review of Scientific Instruments, Volume 67, 1996, Pages 3298-3306.

J.P. Cleveland, S. Manne, D. Bocek, P.K.A. Hansma, A Nondestructive Method for Determining the Spring Constant of Cantilevers for Scanning Force Microscopy, Review of Scientific Instruments, Volume 64, 1993, Pages 403-405.

B. Bhushan, Principles and Applications of Tribology (John Wiley, 1992).

Y.S. Lipatov, Polymer Blends and Interpenetrating Polymer Networks at the Interface with Solids, Progress in Polymer Science, Volume 27, 2002, 1721-1801.

C. Ton-That, A.G. Shard, D.O.H. Teare, R.H. Bradley, XPS and AFM Surface Studies of Solvent-Cast PS/PMMA Blends, Polymer, Volume 42, 2001, Pages 1121-1129.

S. Breakspear, J.R. Smith, T.G. Nevell, J. Tsibouklis, Friction Coefficient Mapping using the Atomic Force Microscope, Surface and Interface Analysis, Volume 36, 2004, Pages 1330-1334.

J.C. Hooton, C.S. German, M. Davies, C.J. Roberts, Comparison of Morphology and Surface Energy Characteristics of Sulfathiazole Polymorphs Based upon Single Particle Studies, European Journal of Pharmaceutical Sciences, Volume 28, 2006, Pages 315-324.

J. Pacifico, K. Endo, S. Morgan, P. Mulvaney, Superhydrophobic Effects of Self-Assembled Monolayers on Micropatterned Surfaces: 3-D Arrays Mimicking the Lotus Leaf, Langmuir, Volume 22, 2006, Pages 11072 -11076.

W.M. Merrill, A.V. Pocius, B.V. Thakker, M. Tirrell, Direct Measurement of Molecular-Level Adhesion Forces Between Biaxially Oriented Solid Polymer-Films, Langmuir, Volume 7, 1991, Pages 1975-1980.

A. Amirfazli, A. Neumann, Status of the Three-Phase Line Tension, Advances in Colloid and Interface Science, Volume 110, 2004, Pages 121-141.

T.D. Blake, The Physics of Moving Wetting Lines, Journal of Colloid and Interface Science, Volume 299, 2006, Pages 1-13.

A. Gajewski, A Method for Contact Angle Measurements under Flow Conditions, International Journal of Heat and Mass Transfer, Volume 48, 2005, Pages 4829-4834.

W. Zisman, Relation of the Equilibrium Contact Angle to Liquid and Solid Constitution, Advances in Chemistry Series, Volume 43, 1963, Pages 1-51.

J. Long, M. Hyder, R. Huang, P. Chen, Thermodynamic Modeling of Contact Angles on Rough, Heterogeneous Surfaces, Advances in Colloid and Interface Science, Volume 118, 2005, Pages 173-190.

R.G. Good, C.J. van Oss, Modern Approaches to Wettability: Theory and Applications (Plenum Press, 1991, pp 1-27.

D.K. Owens, R.C. Wendt, Estimation of the Surface Free Energy of Polymers, Journal of Applied Polymer Science, Volume 13, 1969, Pages 1741-1747.

J.D. Andrade, L.M. Smith, D.E. Gregoris, Surface and Interfacial Aspects of Biomedical Polymers (Plenum Press, 1985, 249-289).

N.A. Burnham, A.J. Kulik, Surface Forces and Adhesion. Handbook of Micro/Nanotribology (CRC Press, 1999, pp 247-271).

K.L. Johnson, K. Kendall, A.D. Roberts, Surface Energy and Contact of Elastic Solids, Proceedings of the Royal Society London A, Volume 324, 1971, Pages 301-313.

B. Derjaguin, V.M. Muller, Y.P. Toporov, Effect of Contact Deformations on Adhesion of Particles, Journal of Colloid and Interface Science, Volume 53, 1975, Pages 314-326.

J. Drelich, G.W. Tormoen, E.R. Beach, Determination of Solid Surface Tension From Particle-Substrate Pull-Off Forces Measured with the Atomic Force Microscope, Journal of Colloid and Interface Science, Volume 280, 2004, Pages 484-497.

J. Israelachvili, Intermolecular and Surface Forces (Academic Press, 1992).

M. Stone, T.G. Nevell, J. Tsibouklis, Surface Energy Characteristics Of Poly(Perfluoroacrylate) Film Structures, Materials Letters, Volume 37, 1998, Pages 102-105.

K. Benzarti, C. Perruchot, M.M. Chehimi, Surface Energetics of Cementitious Materials and their Wettability by an Epoxy Adhesive, Colloids and Surfaces A: Physicochemical and Engineering Aspects, Volume 286, 2006, Pages 78-91.

P. Warszynski, G. Papastavrou, K. Wantke, H. Mohwald, Interpretation of Adhesion Force between Self-Assembled Monolayers Measured by Chemical Force Microscopy, Colloids and Surfaces A: Physicochemical and Engineering Aspects, Volume 214, 2003, Pages 61-75.

O. Noel, M. Brogly, G. Castelein, J. Schultz, In Situ Estimation of the Chemical and Mechanical Contributions in Local Adhesion Force Measurement with AFM: The Specific Case of Polymers, European Polymer Journal, Volume 40, 2004, Pages 965-974.

A. Noy, D.V. Vezenov, C.M. Lieber, Chemical Force Microscopy, Annual Review of Materials Science, Volume 27, 1997, Pages 381-421.

A. Ulman, Formation and structure of self-assembled monolayers. Chemical Reviews, Volume 96, 1996, Pages 1533-1554.

N.K. Chaki, M. Aslam, J. Sharma, K. Vijayamohanan, Applications of self-assembled monolayers in materials chemistry, Proceedings of the Indian Academy of Science, Volume 113, 2001, Pages 659-670.

M.K. Chaudhury, Interfacial Interaction between Low-Energy Surfaces, Materials Science and Engineering, Volume R16, 1996, Pages 97-159.

H. Awada, G. Castelein, M. Brogly, Quantitative Determination of Surface Energry Using Atomic Force Microscopy: The Case of Hydrophobic/Hydrophobic Contact and Hydrophilic/Hydrophilic Contact, Surfaces and Interfacial Analysis, Volume 37, 2005, Pages 755-764.

J. Tsibouklis, T.G. Nevell, Ultra-Low Surface Energy Polymers: The Molecular Design Requirements, Advanced Materials, Volume 15, 2003, Pages 647-650.

J. Singh, J.E. Whitten, Forces between Polymer Surfaces and Self-Assembled Monolayers, Journal of Macromolecular Science, Volume 45, 2008, Pages 885-892.

R.A. Pullin, T.G. Nevell, J. Tsibouklis, Surface Energy Characteristics and Marine Antifouling Performance of Poly(1H, 1H, 2H, 2H-perfluorodecanoyl diitaconate) Film Structures, Materials Letters, Volume 39, 1999, Pages 142-148.

A.A. Thorpe, S.A. Young, T.G. Nevell, J. Tsibouklis, Surface Energy Characteristics of Poly(methylpropenoxyfluoroalkyl siloxane) Film Structures, Applied Surface Science, Volume 136, 1998, Pages 99-104.

P.J. Eaton, J.R. Smith, P. Graham, J.D. Smart, T.G. Nevell, J. Tsibouklis, Adhesion Force Mapping of Polymer Surfaces: Factors Influencing Force of Adhesion, Langmuir, Volume 18, 2002, Pages 3387-3389.

E.R. Beach, G.W. Tormoen, J. Drelich, Pull-Off Forces Measured between Hexadecanethiol Self-Assembled Monolayers in Air using an Atomic Force Microscope: Analysis of Surface Free Energy, Journal of Adhesion Science and Technology, Volume 16, 2002, Pages 845-868.

O. Noel, M. Brogly, G. Castelein, J. Schultz, In Situ Determination of the Thermodynamic Surface Properties of Chemically Modified Surfaces on a Local Scale: an Attempt with the Atomic Force Microscope, Langmuir, Volume 20, 2004, Pages 2707-2712.

D.V. Vezenov, A. Noy, P. Ashby, Chemical Force Microscopy: Probing Chemical Origin of Interfacial Forces and Adhesion, Journal of Adhesion Science and Technology, Volume 19, 2005, Pages 313-364.

M. Brogly, O. Noel, H. Awada, G. Castelein, J.A. Schultz, Nanoscale Study of the Adhesive Contact, Comptes Rendus Chimie, Volume 9, 2006, Pages 99-110.

J.F. Zhang, S. Ebbens, X. Chen, Z. Jin, S. Luk, C. Madden, N. Patel, C.J. Roberts, Determination of the Surface Free Energy of Crystalline and Amorphous Lactose by Atomic Force Microscopy Adhesion Measurement, Pharmaceutical Research, Volume 23, 2006, Pages 401-407.

R. Brunner, I. Etsion, F.E. Talke, A Simple Atomic Force Microscopy Calibration Method for Direct Measurement of Surface Energy on Nanostructured Surfaces Covered with Molecularly Thin Liquid Films, Review of Scientific Instruments, Volume 80, 2009, Article Number 055109.

D.A. Lamprou, J.R. Smith, T.G. Nevell, E. Barbu, C. Stone, C.R. Willis, J. Tsibouklis, A Comparative Study of Surface Energy Data from Atomic Force Microscopy and From Contact Angle Goniometry, Applied Surface Science, Volume 256, 2010, Pages 5082-5087.

D.A. Lamprou, J.R. Smith, T.G. Nevell, E. Barbu, C. Stone, C.R. Willis, R.J. Ewen, J. Tsibouklis, Self-Assembled Alkanethiol Structures on Gold: A Further Insight into the Origins of Structural Rearrangement Phenomena, Surface Science, Volume 604, 2010, Pages 540-547.

D. Lamprou, J.R. Smith, T.G. Nevell, E. Barbu, C.R. Willis, J. Tsibouklis, The Determination of Surface Energy at the Nanoscale: A Further Evaluation of the AFM-Based Approach, Journal of Advanced Microscopy Research, Volume 5, 2010, Pages 137-142.

S.C. Clear, P.F. Nealey, Chemical Force Microscopy Study of Adhesion and Friction between Surfaces Functionalized with Self-Assembled Monolayers and Immersed in Solvents, Journal of Colloid and Interface Science, Volume 213, 1999, Pages 238-250.


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