Open Access Open Access  Restricted Access Subscription or Fee Access

Leaching of Nickel Pig Iron Followed by Precipitation to Synthesize Mixed Sulfate Precipitate


(*) Corresponding author


Authors' affiliations


DOI: https://doi.org/10.15866/irea.v11i5.23084

Abstract


The development of the electric vehicle industry has increased the need for batteries. The NMC (Nickel Manganese Cobalt) battery is one type with superior properties. The nickel used to manufacture NMC batteries is nickel (II) sulfate hexahydrate (NiSO4·6H2O) compounds. A mixed sulfate precipitate should be synthesized to obtain it. Thus, nickel ore has been first smelted in the Mini Blast Furnace, after which the smelted and cooled Nickel Pig Iron (NPI) has been leached into a solution. This study has aimed to analyze the influence of agitation speed and particle size of NPI in the leaching process of mixed sulfate precipitate. The leaching process has used a 2M H2SO4. The leaching temperature is set at 90 °C for 6 hours with agitation speeds of 100, 200, and 300 rpm and particle sizes of -50 μm, +50 -80 μm, and +80 -112 μm. Next, the precipitation process has been carried out by using NaOH solution. Next, the crystallization process has been conducted to eliminate water in the solution and produce powder. The best nickel extraction has been obtained at a particle size of -50 μm at 98.19%.
Copyright © 2023 Praise Worthy Prize - All rights reserved.

Keywords


NMC Battery; Nickel Laterite; Nickel Pig Iron (NPI); Mixed Sulfate Precipitate; Leaching; Sustainable

Full Text:

PDF


References


Bindu, R., Thale, S., Performance Analysis of Power Sharing Control Strategies for Battery/Ultracapacitor Hybrid Energy Storage Based Electric Vehicle, (2020) International Review of Electrical Engineering (IREE), 15 (5), pp. 382-393.
https://doi.org/10.15866/iree.v15i5.18404

El Harouri, K., El Hani, S., El Aissaoui, F., Benbouzid, M., Mediouni, H., Electric Vehicle Charging Station: a Review of Energy Management Systems and Control Type, (2021) International Journal on Energy Conversion (IRECON), 9 (6), pp. 251-266.
https://doi.org/10.15866/irecon.v9i6.21506

Essam Harby, M., Elzoghby, H., Elmasry, S., Elsamahy, A., Bidirectional Control of Electric Vehicles Based on Artificial Neural Network Considering Owners Convenience and Microgrid Stability, (2020) International Review of Automatic Control (IREACO), 13 (6), pp. 304-312.
https://doi.org/10.15866/ireaco.v13i6.19841

Zhang, H., Xue, B., Li, S., Yu, Y., Li, X., Chang, Z., & Su, Y. (2023). Life cycle environmental impact assessment for battery-powered electric vehicles at the global and regional levels. Scientific Reports, 13(1), 7952.
https://doi.org/10.1038/s41598-023-35150-3

Chang, L., Ma, C., Zhang, Y., Li, H., & Xiao, L. (2022). Experimental assessment of the discharge characteristics of multi-type retired lithium-ion batteries in parallel for echelon utilization. Journal of Energy Storage, 55, 105539.
https://doi.org/10.1016/j.est.2022.105539

Van Truong, P., Van Bo, N., Van Tuan, N., Phat, D. T., Dat, N. Q., Van Ky, N., ... & Van Nguyen, T. (2023). Augmenting electrochemical performance of nickel-rich NMC for lithium-ion batteries by combining material synthesis modification and redistribution of transition metal ion concentration. Journal of Physics and Chemistry of Solids, 111616.
https://doi.org/10.1016/j.jpcs.2023.111616

Zhao, K., Gao, F. & Yang, Q. Comprehensive Review on Metallurgical Upgradation Processes of Nickel Sulfide Ores. J. Sustain. Metall. 8, 37-50 (2022).
https://doi.org/10.1007/s40831-022-00501-3

Abdul, F., Firdausi, S., Widyartha, A. B., Setiyorini, Y., & Pintowantoro, S. (2023). The Role of Limestone in Enhancing Selective Reduction of Nickel in the Carbothermic Reduction of Laterite Nickel. Transactions of the Indian Institute of Metals, 1-9.
https://doi.org/10.1007/s12666-023-02938-w

Abdul, F., Iizuka, A., Ho, H. J., Adachi, K., & Shibata, E. (2023). Potential of major by-products from non-ferrous metal industries for CO2 emission reduction by mineral carbonation: a review. Environmental Science and Pollution Research, 1-34.
https://doi.org/10.1007/s11356-023-27898-y

Shuai, W. A. N. G., Jiang, Y., Yufeng, G. U. O., Zhuang, Y. A. N. G., Feng, C. H. E. N., Guang, L. I., & Lingzhi, Y. A. N. G. (2022). Behavior of chromium in the reduction and smelting of high alumina nickel laterite in blast furnace. Journal of Materials Research and Technology.
https://doi.org/10.1016/j.jmrt.2022.12.060

Tian, Q. H., Dong, B., Guo, X. Y., Wang, Q. A., Xu, Z. P., & Li, D. (2023). Valuable metals substance flow analysis in high-pressure acid leaching process of laterites. Journal of Central South University, 30(6), 1776-1786.
https://doi.org/10.1007/s11771-023-5356-y

Abdul, F., Pintowantoro, S., & Maulidani, A. (2020). Analysis the effect of charcoal mass variation to Ni content, sinter strength and yield on sintering process of limonitic laterite nickel ore. Key Engineering Materials, 867, 25-31.
https://doi.org/10.4028/www.scientific.net/KEM.867.25

Abdul, F., Suryandaru, H. V., Saputra, N. D., & Pintowantoro, S. (2021, December). The effect of sulfuric acid concentration on the leaching process of crude Fe-Ni obtained from mini blast furnace process. In AIP Conference Proceedings (Vol. 2384, No. 1, p. 080003). AIP Publishing LLC.
https://doi.org/10.1063/5.0071478

Pintowantoro, S., 2021 Febriana Pintowantoro, S., Waluyo, F. P., Setiyorini, Y., Setyowati, V. A., Kawigraha, A., & Abdul, F. (2021, November). Study of the Effect of Time Variations on the Leaching Process of Ferronickel Products from Mini Blast Furnace to Yield Elements of Fe, Ni, and Co for NiSO4. 6H2O Synthesis. In Journal of Physics: Conference Series (Vol. 2117, No. 1, p. 012024). IOP Publishing.
https://doi.org/10.1088/1742-6596/2117/1/012024

F. Habashi, A short history of hydrometallurgy, Hydrometallurgy, vol. 79, no. 1-2, pp. 15-22, 2005.
https://doi.org/10.1016/j.hydromet.2004.01.008

K. C. Wanta, I. Perdana, and H. T. B. M. Petrus, Evaluation of shrinking core model in leaching process of Pomalaa nickel laterite using citric acid as leachant at atmospheric conditions, IOP Conf. Ser. Mater. Sci. Eng., vol. 162, no. 1, 2016.
https://doi.org/10.1088/1757-899X/162/1/012018

W. Xiao, X. Liu, and Z. Zhao, Kinetics of nickel leaching from low-nickel matte in sulfuric acid solution under atmospheric pressure, Hydrometallurgy, vol. 194, no. August 2019, p. 105353, 2020.
https://doi.org/10.1016/j.hydromet.2020.105353

H. Purwanto, T. Shimada, R. Takahashi, and J. I. Yagi, Recovery of nickel from selectively reduced laterite ore by sulphuric acid leaching, ISIJ Int., vol. 43, no. 2, pp. 181-186, 2003.
https://doi.org/10.2355/isijinternational.43.181

X. Li, W. Monnens, Z. Li, J. Fransaer, and K. Binnemans, Solvometallurgical process for extraction of copper from chalcopyrite and other sulfidic ore minerals, Green Chem., vol. 22, no. 2, pp. 417-426, 2020.
https://doi.org/10.1039/C9GC02983D

T. Agacayak and V. Zedef, Dissolution kinetics of lateritic iron ore in sulphuric acid medium, 9th Int. Multidicsciplinary Sci. Geoconference EXPO - Mod. Manag. Mine Prod. Geol. Environ. Prot. SGEM 2009, vol. 1, pp. 397-404, 2009.

S. Javanshir, Z. H. Mofrad, and A. Azargoon, Atmospheric pressure leaching of nickel from a low-grade nickel-bearing ore, Physicochem. Probl. Miner. Process., vol. 54, no. 3, pp. 890-900, 2018.
https://doi.org/10.5277/ppmp1891

R. Subagja, I. Setiawan, and J. Irawan, Nickel dissolution from nickel matte into the aqueous sulfuric acid solutions, AIP Conf. Proc., vol. 2262, no. September, 2020.
https://doi.org/10.1063/5.0017385

B. Han, B. Altansukh, K. Haga, Y. Takasaki, and A. Shibayama, Leaching and Kinetic Study on Pressure Oxidation of Chalcopyrite in H2SO4 Solution and the Effect of Pyrite on Chalcopyrite Leaching, J. Sustain. Metall., vol. 3, no. 3, pp. 528-542, 2017.
https://doi.org/10.1007/s40831-017-0135-3

R. Elliott, C. A. Pickles, and J. Peacey, Ferronickel particle formation during the carbothermic reduction of a limonitic laterite ore, Miner. Eng., vol. 100, pp. 166-176, 2017.
https://doi.org/10.1016/j.mineng.2016.10.020

M. S. Kim, J. C. Lee, H. S. Park, M. J. Jun, and B. S. Kim, A multistep leaching of nickel-based superalloy scrap for selective dissolution of its constituent metals in hydrochloric acid solutions, Hydrometallurgy, vol. 176, no. December 2017, pp. 235-242, 2018.
https://doi.org/10.1016/j.hydromet.2018.02.002

H. B. T. M. Petrus, K. C. Wanta, H. Setiawan, I. Perdana, and W. Astuti, Effect of pulp density and particle size on indirect bioleaching of Pomalaa nickel laterite using metabolic citric acid, IOP Conf. Ser. Mater. Sci. Eng., vol. 285, no. 1, pp. 0-5, 2018.
https://doi.org/10.1088/1757-899X/285/1/012004

J. Maccarthy, A. Nosrati, W. Skinner, and J. Addai-mensah, Atmospheric acid leaching of nickel laterites : effect of temperature , particle size and mineralogy, 2014.

S. Top, S. Kursunoglu, and Z. T. Ichlas, Effects of leaching parameters on the dissolution of nickel, cobalt, manganese and iron from Caldag lateritic nickel ore in hydrochloric acid solution, Can. Metall. Q., vol. 59, no. 3, pp. 368-376, 2020.
https://doi.org/10.1080/00084433.2020.1780560

Aras and T. Ağaçayak, Dissolution Kinetics of Nickel From Gördes Mani̇sa-Turkey) Lateritic Ore By Sulphuric Acid Leaching Under Effect of Sodium Fluoride, Selcuk Univ. J. Eng., Science Technol., vol. 5, no. 3, pp. 353-361, 2017.
https://doi.org/10.15317/Scitech.2017.95

W. Xuan, A. Otsuki, and A. Chagnes, Investigation of the leaching mechanism of NMC 811 (LiNi0.8Mn0.1Co0.1O2) by hydrochloric acid for recycling lithium ion battery cathodes, RSC Adv., vol. 9, no. 66, pp. 38612-38618, 2019.
https://doi.org/10.1039/C9RA06686A

S. Ghosh et al., Growth and characterization of ammonium nickel-copper sulfate hexahydrate: A new crystal of Tutton's salt family for the application in solar-blind technology, Opt. Mater. (Amst)., vol. 85, no. September, pp. 425-437, 2018.
https://doi.org/10.1016/j.optmat.2018.09.004

Sole, K.C. (2018). The Evolution of Cobalt-Nickel Separation and Purification Technologies: Fifty Years of Solvent Extraction and Ion Exchange. In: Davis, B., et al. Extraction 2018. The Minerals, Metals & Materials Series. Springer, Cham.
https://doi.org/10.1007/978-3-319-95022-8_95

R. T. Jayanti, P. Industri, L. Morowali, and E. Technology, Effect of Agitation Speed and Leaching Time for Nickel Recovery of Morowali Limonite Ore in Atmospheric Citric Acid Leaching, Proceedings of the 2nd Faculty of Industrial Technology International Congres International Conference, Bandung, Indonesia, January 28-30, 2020, pp. 2-7, 2020.

McKinsey, The future of nickel: a class act, Basic Mater., no. November, pp. 1-16, 2017.

Fulesa, AM, Setiyorini, Y., Abdul, F., Pintowantoro, S., 2023, Effect of Time Stepping in the Filtering Process on the Synthesis of Nickel Sulfate Powder from Blast Furnace Ferronickel, Applied Science and Engineering Progress, Vol. 17, n. 1.
https://doi.org/10.14416/j.asep.2023.06.002


Refbacks

  • There are currently no refbacks.



Please send any question about this web site to info@praiseworthyprize.com
Copyright © 2005-2024 Praise Worthy Prize