Alignment Nanofibers Conducting Polymer (PAni.CSA/PEO) Preparation by Electrospinning Technique


(*) Corresponding author


Authors' affiliations


DOI's assignment:
the author of the article can submit here a request for assignment of a DOI number to this resource!
Cost of the service: euros 10,00 (for a DOI)

Abstract


Importance of different concentration parameter was evaluated in electrospinning of PAni.CSA/PEO Blends, The alignment nanofibers of this blends were successfully fabricated using electrospinning technique. Morphology and diameters of the nanofibers were studied by Atomic Force Microscope (AFM). The diameter of nanfiber was about 40.49 nm (at 8 wt% PEO concentration) and increased with increasing concentration to 92.35 nm (at 30 wt% PEO concentration).  Structural characteristics of the electrospuning nanofibers and the formation of functional group of PEO polymer and the PAni.CSA were predicted by the FT-IR spectra. X-ray diffraction (XRD) showed crystalline peaks of the PAni.CSA/PEO blends. The PAni.CSA/PEO blends containing up to the 8 wt% PEO could be electrospun into the continuous fibers structure, although pure PAni.CSA solution was not able to be electrospuning into the fibrous structure.
Copyright © 2013 Praise Worthy Prize - All rights reserved.

Keywords


Electrospinning; PAni.CSA/PEO; Conducting Polymer; Nanofibers

Full Text:

PDF


References


Y. Z. Zhang et al, Biomimetic and Bioactive Nanofibrous Scaffolds from Electrospun Composite Nanofibers, Int. J. Nanomedicine 2(4) (2007), 623–638.

J. B. Veluru et al, Electrical Properties of Electrospun Fibers of PANI/PMMA Composites, Journal of Engineered Fibers and Fabrics 2(2) (2007), 25-31.

J.M. Deitzel et al, The Effect of Processing Variables on the Morphology of Electrospun Nanofibers and Textiles, Polymer 42(1) (2001), 261–272.

J. Huang, Syntheses and Applications of Conducting Polymer Polyaniline Nanofibers, Pure Appl. Chem. 78(1) (2006), 15–27.

M. R. Abdul Wahab, M. Din, K. Jusoff , Surface Plasmon Resonance Study on the Characteristics of a Conducting Polymer Ultra-thin Film, (2009) International Review of Physics (IREPHY), 3 (4), pp. 228-232.

S. Ramakrishna et al, An Introduction to Electrospinning and Nanofibers, (World Scientific Publishing Co. Pte. Ltd, 2005).

Jingwei Xie, Younan Xia, Electrospinning: An Enabling Technique for Nanostructured Materials, Material Matters 3(1) (2008), 19-23.

J. A. Matthews et al, Electrospinning of Collagen Nanofibers, Biomacromolecules 3 (2) (2002), 232-238.

A. Theron et al, Electrostatic Field-Assisted Alignment of Electrospun Nanofibres, Nanotechnology 12 (2001), 384–390.

M. Jayakannan et al, Synthesis and Characterization of New Azobenzenesulfonic Acids Doped Conducting Polyaniline, European Polymer Journal 42(2006) 2623-2631.

R. A, Talib, Prepation of Conducting polymer (PAni) by Chemical Method and Study same of Physical Properties and its Application as Ammonia Gas Sensor, MS.c Thesis, University of Basrah, College of Science, Physics Department, Basra, Iraq , 2009

N. J. Pinto et al, Electrospun Polyaniline/Polyethylene Oxide Nanofiber Field-Effect Transistor, Appl. Phys. Lett. 83 (2003), 4244-4246

I. D. Norris et al, Fabrication of Ultrafine Conducting Fibers: Polyaniliner polyethylene Oxide Blends, Synthetic Metals 114(2000), 109–114.

M. Li et al, Electrospinning Polyaniline-Contained Gelatin Nanofibers for Tissue Engineering Applications, Biomaterials 27 (2006), 2705–2715.

P. Heikkilä, A. Harlin, Parameter Study of Electrospinning of Polyamide-6, European Polymer Journal 44 (2008), 3067–3079.

H. Sharma, Conducting Polymers: Polyaniline, its state of the art and application, MS.c. Thesis, Thapar Institute of Engineering and Technology, Deemed University, Punjab, 2006.

S. Kim et al, An Experimental Study on the Effect of Mesoporous Silica Addition Onion Conductivity of Poly(ethylene oxide) Electrolytes, Current Applied Physics 8 (2008), 729–731.

A. Dey et al, Molecular Interaction and Ionic Conductivity of Polyethylene oxide–LiClO4 Nanocomposites, Journal of Physics and Chemistry of Solids 71(2010), 329–335.

M. Irimia-Vladu, J. W. Fergus, Suitability of Emeraldine Base Polyaniline-PVA Composite Film for Carbon Dioxide Sensing, Synthetic Metals 156 (2006), 1401–1407.

H. K. Chaudhari. D. S. Kelkar, Properties of Metal-Polyaniline Schottky Barriers, J. Appl. Polym. Sci . 61(3) (1996) 561–565.

K. S. Ryu et al, Physicochemical and Electrical Characterization of Polyaniline Induced by Crosslinking, Stretching, and Doping Bull, Korean Chem. Soc. 20(3) (1999), 333-336.

A.G. MacDiarmid and A.J. Epstein ,Polyaniline : Synthesis, Chemistry and Processing, Office of Naval Research, Published in , New Aspects of Organic Chemistry II, Z. Yoshido and Y. Ohshiro, Eds., VCH (Weinheim) and Kodansha (Tokyo) - Co publishers, (1992), 271.

X. Zong et al, Structure and Process Relationship of Electrospun Bioabsorbable Nanofiber membranes, Polymer 43(2002), 4403–4412.

O. Ero-Phillips et al, Tailoring Crystallinity of Electrospun Plla Fibres by Control of Electrospinning Parameters, Polymers 4(2012),1331-1348.

Jeno Sólyom, Fundamentals of the Physics of Solids, (Springer-Verlag Berlin Heidelberg, 2007).

B.D. Cullity and S.R. Stock, Elements of X – Ray Diffraction, 3th edition, (Prentice-Hall in the United States of America, 2001).

S. Zhao et al, Electrospinning of Ethyl-cyanoethyl Cellulose/Tetrahydrofuran Solutions, J. Appl. Polym. Sci. 91(2004) 242–246.

J. McMurry, Fundamentals of Organic Chemistry, 5th edition (Thomson Learning Inc. USA. 2008).

M. MacDiarmrid et al, Polyaniline: Anovel Class of Conducting Polymers, Faraday Discussion 88(1989) 317-332.

Chia-Chi Su, Yun-Hwei Shen, Adsorption of Poly(ethylene oxide) on Smectite: Effect of Layer Charge, J Colloid Interface Sci .332(1)(2009),11-5.

C. H. Manoratne et al, Ionic Conductivity of Poly(ethylene oxide) (PEO)- Montmorillonite (MMT) Nanocomposites Prepared by Intercalation from Aqueous Medium, Int. J. Electrochem. Sci. 1 (2006), 32-46.

H. Kunteppa et al, Synthesis and Morphological Change in poly(ethyleneoxide) –sodiumchlorate Based Polymer Electrolyte Complex with Polyaniline, Physica B 406 (2011), 3997–4000.

N. Gondaliya et al, Structural and Conductivity Studies of Poly(Ethylene Oxide)—Silver Triflate Polymer Electrolyte System, Materials Sciences and Applications 2(2011),1639-1643.

A. R. Subrahmanyam et al , Mechanical and Electrical Conductivity Studies of PANI-PVA and PANI-PEO Blends, International Journal of Material Science 2(1) (2012), 27-30.

C. Tuncer et al¸ Poly(ethylene oxide) and its Blends with Sodium Alginate, Polymer 46 (2005), 10750–10757.

K. M. Ziadan et al, Study of the Electrical Characteristics of Polyaniline Prepared by Electrochemical Polymerization, Energy Procedia 19 ( 2012), 71–79.

K. Gupta et al, Optical and Electrical Transport Properties of Polyaniline–Silver Nanocomposite, Synthetic Metals 160 (2010), 1566–1573.

B.T. Raut et al, Novel Method of Fabrication of Polyaniline–CdS Nanocomposites: Structural, Morphological and Optoelectronic Properties, Ceramics International 38 (2012), 3999–4007.

K. Mallick et al, Electrical and Optical Properties of polyaniline with a Weblink Morphology, Journal of Applied Polymer Science 116 (2010), 1587-1592.

P. Rannou, M. Nechtschein, PANI-CSA films: Ageing and Kinetics of Conductivity Degradation, J. Chim. Phys. 95 (1998), 1410-1413.

L.Sanjay et al, Effect of Camphor Sulfonic Acid Doping on Structural, Morphological, Optical and Electrical Transport Properties on Polyaniline-ZnO Nanocomposites , Soft Nanoscience Letters 2(2012) 46-53.

P. Y. Bruice, Organic Chemistry, 6th edition, (Perntice Hall ,USA, 2011)


Refbacks

  • There are currently no refbacks.



Please send any question about this web site to info@praiseworthyprize.com
Copyright © 2005-2024 Praise Worthy Prize